Fabrication of electrospun polyamide–weathered basalt nano-composite as a non-conventional membrane for basic and acid dye removal

• Published in: Polymer bulletin (Berlin, Germany) Germany), 2023-08, Vol.80 (8), p.8511-8533
• Main Authors: El-Sheikh, M. N., Metwally, Bahaa S., Mubarak, Mahmoud. F., Ahmed, Hanan A., Abdel Moghny, Thanaa, Zayed, Ahmed M.
• Format: Article
• Language: English
• Subjects: Acid dyes; Acids; Adsorptivity; Basalt; Biodegradation; Cellulose acetate; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Complex Fluids and Microfluidics; Dyes; Efficiency; Electrospinning; Environmental impact; Factories; Fourier transforms; Infrared analysis; Mechanical properties; Membrane separation; Membranes; Methylene blue; Nanocomposites; Organic Chemistry; Original Paper; Physical Chemistry; Polyamide resins; Polymer Sciences; Polymers; Polyvinyl alcohol; Power supply; Rejection; Room temperature; Soft and Granular Matter; Textiles; Wastewater treatment
• ISSN: 0170-0839; 1436-2449
• DOI: 10.1007/s00289-022-04459-w

In this study, an adsorptive electrospun polyamide membrane (ESPA) and electrospun polyamide–weathered basalt composite membrane (ESPA-WB) were prepared by an electrospinning process at room temperature. Hence, the WB structure was built as a polymeric membrane separation film in combination with the ESPA matrix as a composite nano-filtration membrane. Then, the ESPA and ESPA-WB membranes were characterized using BET surface area analysis, Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy (SEM). To avoid cracks forming during the sintering process, the WB should be added in certain percentages. The microstructures of the prepared membranes were investigated to evaluate their efficiency for basic and acidic dyesʼ removal and their permeation flux. Compared with the ESPA, the ESPA-WB membrane combines the characteristics of WB and ESPA, which greatly enhances the performance of both methylene blue (MB) and methyl orange (MO) dyes removal from synthetic wastewater. The outcomes of this study indicated that the dye uptake in the case of ESPA-WB is higher than that of ESPA, and it decreases with an increase in dye concentrations. The obtained membrane ESPA-WB showed both an excellent anti-dye fouling and a good rejection property for both dyes (i.e. 90% rejection for MB and 74% for MO) with no sign of contamination by the applied dyes. It was found that the structure of the ESPA-WB membrane contains a large number of several adsorption sites which leads to an increase in the removal rate of dyes. Hence, this study demonstrated a non-conventional strategy to prepare an effective adsorptive nano-composite membrane that can be applied as a highly recyclable one for the removal of organic dyes. Graphic abstract