Specific MARY spectrum from radical anion of pentafluorobenzene

The paper presents the first resolved experimental magnetically affected reaction yield (MARY) spectrum for a system with nonequivalent nuclei, radical anion of pentafluorobenzene. This observation dispels the common apprehension that because of a rather involved energy level layout a system with no...

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Bibliographic Details
Published in:Applied magnetic resonance 2006-06, Vol.30 (3-4), p.549-554
Main Authors: Kalneus, E. V., Kipriyanov, A. A., Purtov, P. A., Stass, D. V., Molin, Yu. N.
Format: Article
Language:English
Subjects:
Anions
Energy levels
Nuclei
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Summary:The paper presents the first resolved experimental magnetically affected reaction yield (MARY) spectrum for a system with nonequivalent nuclei, radical anion of pentafluorobenzene. This observation dispels the common apprehension that because of a rather involved energy level layout a system with not all nuclei magnetically equivalent cannot produce resolved MARY lines in nonzero fields, and greatly, increases the practical scope of level-crossing techniques for studies of spin-correlated radical pairs. The experimental finding is supported by schemes of energy levels calculated for this system.
ISSN:0937-9347
1613-7507
DOI:10.1007/BF03166217