ESR study of some iminoxy free radicals generated from phosphorylated oximes and dioximes

The new type of phosphoniminoxy free radicals was generated electrochemically or by chemical oxidation of oximes. It was established the strong difference of ESR parameters for isomeric Z and E forms of the radicals. The spin distribution and its correlation with electronic and spatial characteristi...

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Bibliographic Details
Published in:Applied magnetic resonance 1998-06, Vol.14 (4), p.489-496
Main Authors: Il’yasov, A. V., Vafina, A. A., Breuer, E., Hägele, G.
Format: Article
Language:English
Subjects:
Electron spin
Free radicals
Oxidation
Oximes
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Summary:The new type of phosphoniminoxy free radicals was generated electrochemically or by chemical oxidation of oximes. It was established the strong difference of ESR parameters for isomeric Z and E forms of the radicals. The spin distribution and its correlation with electronic and spatial characteristics of molecules as well as with intramolecular interactions are discussed.
ISSN:0937-9347
1613-7507
DOI:10.1007/BF03161857