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Removal of various anionic dyes using sodium alginate/poly(N-vinyl-2-pyrrolidone) blend hydrogel beads
In this study, novel blend hydrogel beads were prepared for the use in removal of anionic textile dyes due to their hazardous impact to nature. Sodium alginate and sodium alginate/poly( N -vinyl-2-pyrrolidone) beads were prepared by gelation method into calcium chloride solution. Prepared blend bead...
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| Published in: | Polymer bulletin (Berlin, Germany) Germany), 2015-07, Vol.72 (7), p.1735-1752 |
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| Main Authors: | , |
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| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c316t-b5d6f8d2a10915cb83c085c6fedb0034c6df0d47a80288593f2eba5f739e54a83 |
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| cites | cdi_FETCH-LOGICAL-c316t-b5d6f8d2a10915cb83c085c6fedb0034c6df0d47a80288593f2eba5f739e54a83 |
| container_end_page | 1752 |
| container_issue | 7 |
| container_start_page | 1735 |
| container_title | Polymer bulletin (Berlin, Germany) |
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| creator | İnal, Murat Erduran, Nuran |
| description | In this study, novel blend hydrogel beads were prepared for the use in removal of anionic textile dyes due to their hazardous impact to nature. Sodium alginate and sodium alginate/poly(
N
-vinyl-2-pyrrolidone) beads were prepared by gelation method into calcium chloride solution. Prepared blend beads were characterized by TGA and FTIR analysis, and they were successfully used in adsorption of the reactive red-120 (RR), cibacron brilliant red 3B-A (CBR) and remazol brilliant blue R (RBB) in batch system. The effects of various parameters such as pH, initial dye concentration, contact time and temperature onto adsorption were investigated. The maximum adsorption capacities were found 116.8, 73.3 and 55.3 mg g
−1
for RR, CBR and RBB, respectively. The adsorption of dyes was well described by pseudo-second-order kinetics and Langmuir isotherm. Thermodynamic parameters indicated that the adsorption is spontaneous and exothermic. These results have shown that blend hydrogel beads can be effectively used as adsorbent in the removal of dyes from harmful wastewaters. |
| doi_str_mv | 10.1007/s00289-015-1367-7 |
| format | article |
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N
-vinyl-2-pyrrolidone) beads were prepared by gelation method into calcium chloride solution. Prepared blend beads were characterized by TGA and FTIR analysis, and they were successfully used in adsorption of the reactive red-120 (RR), cibacron brilliant red 3B-A (CBR) and remazol brilliant blue R (RBB) in batch system. The effects of various parameters such as pH, initial dye concentration, contact time and temperature onto adsorption were investigated. The maximum adsorption capacities were found 116.8, 73.3 and 55.3 mg g
−1
for RR, CBR and RBB, respectively. The adsorption of dyes was well described by pseudo-second-order kinetics and Langmuir isotherm. Thermodynamic parameters indicated that the adsorption is spontaneous and exothermic. These results have shown that blend hydrogel beads can be effectively used as adsorbent in the removal of dyes from harmful wastewaters.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-015-1367-7</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Acids ; Adsorbents ; Adsorption ; Calcium chloride ; Characterization and Evaluation of Materials ; Chemicals ; Chemistry ; Chemistry and Materials Science ; Chloride ; Complex Fluids and Microfluidics ; Dyes ; Environmental impact ; Equilibrium ; Exothermic reactions ; Hydrogels ; Membrane separation ; Organic Chemistry ; Original Paper ; Oxidation ; Parameters ; Physical Chemistry ; Polymer Sciences ; Polymers ; Sodium alginate ; Soft and Granular Matter ; Textile industry ; Usability</subject><ispartof>Polymer bulletin (Berlin, Germany), 2015-07, Vol.72 (7), p.1735-1752</ispartof><rights>Springer-Verlag Berlin Heidelberg 2015</rights><rights>Springer-Verlag Berlin Heidelberg 2015.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-b5d6f8d2a10915cb83c085c6fedb0034c6df0d47a80288593f2eba5f739e54a83</citedby><cites>FETCH-LOGICAL-c316t-b5d6f8d2a10915cb83c085c6fedb0034c6df0d47a80288593f2eba5f739e54a83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>İnal, Murat</creatorcontrib><creatorcontrib>Erduran, Nuran</creatorcontrib><title>Removal of various anionic dyes using sodium alginate/poly(N-vinyl-2-pyrrolidone) blend hydrogel beads</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>In this study, novel blend hydrogel beads were prepared for the use in removal of anionic textile dyes due to their hazardous impact to nature. Sodium alginate and sodium alginate/poly(
N
-vinyl-2-pyrrolidone) beads were prepared by gelation method into calcium chloride solution. Prepared blend beads were characterized by TGA and FTIR analysis, and they were successfully used in adsorption of the reactive red-120 (RR), cibacron brilliant red 3B-A (CBR) and remazol brilliant blue R (RBB) in batch system. The effects of various parameters such as pH, initial dye concentration, contact time and temperature onto adsorption were investigated. The maximum adsorption capacities were found 116.8, 73.3 and 55.3 mg g
−1
for RR, CBR and RBB, respectively. The adsorption of dyes was well described by pseudo-second-order kinetics and Langmuir isotherm. Thermodynamic parameters indicated that the adsorption is spontaneous and exothermic. These results have shown that blend hydrogel beads can be effectively used as adsorbent in the removal of dyes from harmful wastewaters.</description><subject>Acids</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Calcium chloride</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemicals</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chloride</subject><subject>Complex Fluids and Microfluidics</subject><subject>Dyes</subject><subject>Environmental impact</subject><subject>Equilibrium</subject><subject>Exothermic reactions</subject><subject>Hydrogels</subject><subject>Membrane separation</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Oxidation</subject><subject>Parameters</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Sodium alginate</subject><subject>Soft and Granular Matter</subject><subject>Textile industry</subject><subject>Usability</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhoMouH78AG8BL3qIO2natDnK4hcsCqLnkDZJzdJNarJd6L-3SwVPnoaB93mHeRC6onBHAcplAsgqQYAWhDJekvIILWjOOMnyXByjBdASCFRMnKKzlDYw7ZzTBbLvZhv2qsPB4r2KLgwJK--Cdw3Wo0l4SM63OAXthi1WXeu82pllH7rx5pXsnR87kpF-jDF0TgdvbnHdGa_x16hjaE2Ha6N0ukAnVnXJXP7Oc_T5-PCxeibrt6eX1f2aNIzyHakLzW2lM0VB0KKpK9ZAVTTcGl0DsLzh2oLOS1VN31aFYDYztSpsyYQpclWxc3Q99_YxfA8m7eQmDNFPJ2UmaCk45SCmFJ1TTQwpRWNlH91WxVFSkAedctYpJ53yoFOWE5PNTJqyvjXxr_l_6AcMQHjU</recordid><startdate>20150701</startdate><enddate>20150701</enddate><creator>İnal, Murat</creator><creator>Erduran, Nuran</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20150701</creationdate><title>Removal of various anionic dyes using sodium alginate/poly(N-vinyl-2-pyrrolidone) blend hydrogel beads</title><author>İnal, Murat ; Erduran, Nuran</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-b5d6f8d2a10915cb83c085c6fedb0034c6df0d47a80288593f2eba5f739e54a83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Acids</topic><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Calcium chloride</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemicals</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chloride</topic><topic>Complex Fluids and Microfluidics</topic><topic>Dyes</topic><topic>Environmental impact</topic><topic>Equilibrium</topic><topic>Exothermic reactions</topic><topic>Hydrogels</topic><topic>Membrane separation</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Oxidation</topic><topic>Parameters</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Sodium alginate</topic><topic>Soft and Granular Matter</topic><topic>Textile industry</topic><topic>Usability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>İnal, Murat</creatorcontrib><creatorcontrib>Erduran, Nuran</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>İnal, Murat</au><au>Erduran, Nuran</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Removal of various anionic dyes using sodium alginate/poly(N-vinyl-2-pyrrolidone) blend hydrogel beads</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. 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N
-vinyl-2-pyrrolidone) beads were prepared by gelation method into calcium chloride solution. Prepared blend beads were characterized by TGA and FTIR analysis, and they were successfully used in adsorption of the reactive red-120 (RR), cibacron brilliant red 3B-A (CBR) and remazol brilliant blue R (RBB) in batch system. The effects of various parameters such as pH, initial dye concentration, contact time and temperature onto adsorption were investigated. The maximum adsorption capacities were found 116.8, 73.3 and 55.3 mg g
−1
for RR, CBR and RBB, respectively. The adsorption of dyes was well described by pseudo-second-order kinetics and Langmuir isotherm. Thermodynamic parameters indicated that the adsorption is spontaneous and exothermic. These results have shown that blend hydrogel beads can be effectively used as adsorbent in the removal of dyes from harmful wastewaters.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-015-1367-7</doi><tpages>18</tpages></addata></record> |
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| ispartof | Polymer bulletin (Berlin, Germany), 2015-07, Vol.72 (7), p.1735-1752 |
| issn | 0170-0839 1436-2449 |
| language | eng |
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| subjects | Acids Adsorbents Adsorption Calcium chloride Characterization and Evaluation of Materials Chemicals Chemistry Chemistry and Materials Science Chloride Complex Fluids and Microfluidics Dyes Environmental impact Equilibrium Exothermic reactions Hydrogels Membrane separation Organic Chemistry Original Paper Oxidation Parameters Physical Chemistry Polymer Sciences Polymers Sodium alginate Soft and Granular Matter Textile industry Usability |
| title | Removal of various anionic dyes using sodium alginate/poly(N-vinyl-2-pyrrolidone) blend hydrogel beads |
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