Ternary nanocomposites based on plasticized poly(3-hydroxybutyrate) and nanocellulose

Poly(3-hydroxybutyrate) (PHB) ternary nanocomposites were obtained by solvent-casting method. The current work compares the behavior of nanocomposites made with two different plasticizers and two types of nanocellulose (cellulose nanocrystals—CNC—and bacterial cellulose—BC). A traditional plasticize...

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Bibliographic Details
Published in:Polymer bulletin (Berlin, Germany) Germany), 2019-02, Vol.76 (2), p.967-988
Main Authors: Seoane, I. T., Cerrutti, P., Vazquez, A., Cyras, V. P., Manfredi, L. B.
Format: Article
Language:English
Subjects:
Additives
Biodegradation
Biopolymers
Cellulose
Cellulosic resins
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Complex Fluids and Microfluidics
Crystallization
Environmental impact
Ethylene glycol
Fourier transforms
Mechanical properties
Molecular weight
Nanocomposites
Nanocrystals
Nanoparticles
Nucleation
Organic Chemistry
Original Paper
Physical Chemistry
Plasticizers
Polyesters
Polyhydroxybutyrate
Polymer Sciences
Polymers
Soft and Granular Matter
Temperature
Thermal stability
Water vapor
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Summary:Poly(3-hydroxybutyrate) (PHB) ternary nanocomposites were obtained by solvent-casting method. The current work compares the behavior of nanocomposites made with two different plasticizers and two types of nanocellulose (cellulose nanocrystals—CNC—and bacterial cellulose—BC). A traditional plasticizer (glyceryl tributyrate—TB) and a polymeric one (poly[di(ethylene glycol) adipate]—A) were chosen in order to evaluate the responses of PHB properties to the addition of plasticizers with different molecular weight. Additionally, the influences of CNC and BC on the properties of the plasticized polymer were compared. Cellulose nanocrystals were determined as effective PHB nucleation agents when TB was added to the samples. On the other hand, the addition of A and CNC seems to retard PHB nucleation but enhances the thermal stability of the samples due to the intrinsic stability of the additives. A counterbalanced effect of TB plasticizer and CNC was observed in the mechanical and water vapor permeation properties. The addition of BC to the plasticized samples showed the highest detriment in thermal stability of PHB due to its poor dispersion. It was concluded that PHB/TB/CNC nanocomposites will be suitable materials for using as packaging in single-use applications, showing an appropriate balance among barrier, thermal, and mechanical properties.
ISSN:0170-0839
1436-2449
DOI:10.1007/s00289-018-2421-z