Function Graded Carbon Micro‐Structures for Powerless Photon Sensing with Intriguing µm‐Scale Position Sensitivity

• Published in: Advanced optical materials 2024-01, Vol.12 (2), p.n/a
• Main Authors: Karamati, Amin, Qu, Wangda, Bai, Xianglan, Wang, Xinwei
• Format: Article
• Language: English
• Subjects: Aerogels; Bias; Carbon; carbon microfibers; Coefficient of variation; Graphene; graphene aerogel fibers; graphene microfibers; Lasers; Microfibers; Photons; Position sensing; position‐sensitive photon sensing; Seebeck coefficient; Seebeck effect; Sensitivity
• ISSN: 2195-1071; 2195-1071
• DOI: 10.1002/adom.202301377

Partial laser treatment is introduced to carbon‐based microfibers to generate excellent photon sensing capability without bias. This treatment brings about a Seebeck coefficient distribution along the sample's length, out of which a photovoltage with no external bias is generated and sensed. Using a line‐shaped laser spot, carbon microfiber (CMF), graphene microfiber (GMF), and graphene aerogel fiber (GAF) are investigated for their response to µm‐scale photon irradiation. A higher sensitivity for the incident photon is found for the GAF with no position sensitivity. More Seebeck coefficient variation is also observed for the GAF considering the amount of laser power used for the laser treatment. A weaker Seebeck coefficient spatial variation is observed for the GMF compared with the GAF. However, its photovoltage shows an abrupt magnitude change from the laser‐treated region to the non‐treated one. Despite the low spatial variation of the Seebeck coefficient for the CMF, it features an excellent and accurate position‐sensitive photoresponse with polarization change over a distance of ≈100 µm. Such unique capability prompts novel applications in using partially annealed CMF for sensing the position of optical beams at the microscale. Partial laser treatment is applied to carbon microfiber (CMF) to generate excellent photon sensing capability without bias. During this procedure, one‐half of the microfiber is laser‐annealed, while the other is left intact. A Seebeck coefficient distribution comes about for the CMF, resulting in excellent and accurate position‐sensitive photoresponse with polarization change over a distance of ≈ 100 µm.