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Wittig-horner reactions on styrene-divinylbenzene supports with benzaldehyde side-groups
SummaryA styrene-divinylbenzene copolymer functionalized with aldehyde was prepared under phase transfer catalyzed (PTC) conditions. A statistical method for the calculation of the degree of functionalization with aldehyde groups is proposed. The degree of functionalization with aldehyde groups is r...
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| Published in: | Polymer bulletin (Berlin, Germany) Germany), 2006-06, Vol.57 (2), p.189-197 |
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| Main Authors: | , , , , , , |
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| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c303t-574f1dac067ffb20edb8d3ca450853891189b6f00585797fb0afdad9cc9f567e3 |
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| cites | cdi_FETCH-LOGICAL-c303t-574f1dac067ffb20edb8d3ca450853891189b6f00585797fb0afdad9cc9f567e3 |
| container_end_page | 197 |
| container_issue | 2 |
| container_start_page | 189 |
| container_title | Polymer bulletin (Berlin, Germany) |
| container_volume | 57 |
| creator | POPA, Adriana ILIA, Gheorghe DAVIDESCU, Corneliu-Mircea ILIESCU, Smaranda PLESU, Nicoleta PASCARIU, Aurelia ZHENGPU ZHANG |
| description | SummaryA styrene-divinylbenzene copolymer functionalized with aldehyde was prepared under phase transfer catalyzed (PTC) conditions. A statistical method for the calculation of the degree of functionalization with aldehyde groups is proposed. The degree of functionalization with aldehyde groups is relatively high.Styrene-divinylbenzene polymers functionalized with benzaldehyde groups were used in Wittig-Horner reaction, in order to introduce double bonds on polymers. The reactions were carried out using PTC method, solid-liquid-solid (s-l-s) (K2CO3, tetrahydrofuran, tetraethylammonium iodide) system. Phase transfer catalyzed reactions are often more easily and cheaply carried out than conventional method and they are therefore of particular interest. |
| doi_str_mv | 10.1007/s00289-006-0553-z |
| format | article |
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A statistical method for the calculation of the degree of functionalization with aldehyde groups is proposed. The degree of functionalization with aldehyde groups is relatively high.Styrene-divinylbenzene polymers functionalized with benzaldehyde groups were used in Wittig-Horner reaction, in order to introduce double bonds on polymers. The reactions were carried out using PTC method, solid-liquid-solid (s-l-s) (K2CO3, tetrahydrofuran, tetraethylammonium iodide) system. Phase transfer catalyzed reactions are often more easily and cheaply carried out than conventional method and they are therefore of particular interest.</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-006-0553-z</identifier><identifier>CODEN: POBUDR</identifier><language>eng</language><publisher>Heidelberg: Springer</publisher><subject>Aldehydes ; Applied sciences ; Benzaldehyde ; Chemical modifications ; Chemical reactions ; Chemical reactions and properties ; Copolymers ; Divinylbenzene ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polymers ; Statistical methods ; Styrenes ; Tetrahydrofuran</subject><ispartof>Polymer bulletin (Berlin, Germany), 2006-06, Vol.57 (2), p.189-197</ispartof><rights>2007 INIST-CNRS</rights><rights>Springer-Verlag 2006.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c303t-574f1dac067ffb20edb8d3ca450853891189b6f00585797fb0afdad9cc9f567e3</citedby><cites>FETCH-LOGICAL-c303t-574f1dac067ffb20edb8d3ca450853891189b6f00585797fb0afdad9cc9f567e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17828265$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>POPA, Adriana</creatorcontrib><creatorcontrib>ILIA, Gheorghe</creatorcontrib><creatorcontrib>DAVIDESCU, Corneliu-Mircea</creatorcontrib><creatorcontrib>ILIESCU, Smaranda</creatorcontrib><creatorcontrib>PLESU, Nicoleta</creatorcontrib><creatorcontrib>PASCARIU, Aurelia</creatorcontrib><creatorcontrib>ZHENGPU ZHANG</creatorcontrib><title>Wittig-horner reactions on styrene-divinylbenzene supports with benzaldehyde side-groups</title><title>Polymer bulletin (Berlin, Germany)</title><description>SummaryA styrene-divinylbenzene copolymer functionalized with aldehyde was prepared under phase transfer catalyzed (PTC) conditions. A statistical method for the calculation of the degree of functionalization with aldehyde groups is proposed. The degree of functionalization with aldehyde groups is relatively high.Styrene-divinylbenzene polymers functionalized with benzaldehyde groups were used in Wittig-Horner reaction, in order to introduce double bonds on polymers. The reactions were carried out using PTC method, solid-liquid-solid (s-l-s) (K2CO3, tetrahydrofuran, tetraethylammonium iodide) system. Phase transfer catalyzed reactions are often more easily and cheaply carried out than conventional method and they are therefore of particular interest.</description><subject>Aldehydes</subject><subject>Applied sciences</subject><subject>Benzaldehyde</subject><subject>Chemical modifications</subject><subject>Chemical reactions</subject><subject>Chemical reactions and properties</subject><subject>Copolymers</subject><subject>Divinylbenzene</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers</subject><subject>Statistical methods</subject><subject>Styrenes</subject><subject>Tetrahydrofuran</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNpFkEtLxDAUhYMoOI7-AHcFcRm9aZomWcrgCwbcKLoLaR4zGcamJq3S-fV2GMHV5dx7zrnwIXRJ4IYA8NsMUAqJAWoMjFG8O0IzUtEal1Ulj9EMCAcMgspTdJbzBiZd12SGPt5D34cVXsfUulQkp00fYpuL2Ba5H5NrHbbhO7TjtnHtbpJFHroupj4XP6FfF_ut3lq3Hu10CtbhVYpDl8_Ridfb7C7-5hy9Pdy_Lp7w8uXxeXG3xIYC7THjlSdWG6i5900JzjbCUqMrBoJRIQkRsqk9ABOMS-4b0N5qK42RntXc0Tm6OvR2KX4NLvdqE4fUTi9VKYkARqCkk4scXCbFnJPzqkvhU6dREVB7gOoAUE0A1R6g2k2Z679mnY3e-qRbE_J_kItSlDWjv7fvctw</recordid><startdate>20060601</startdate><enddate>20060601</enddate><creator>POPA, Adriana</creator><creator>ILIA, Gheorghe</creator><creator>DAVIDESCU, Corneliu-Mircea</creator><creator>ILIESCU, Smaranda</creator><creator>PLESU, Nicoleta</creator><creator>PASCARIU, Aurelia</creator><creator>ZHENGPU ZHANG</creator><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20060601</creationdate><title>Wittig-horner reactions on styrene-divinylbenzene supports with benzaldehyde side-groups</title><author>POPA, Adriana ; ILIA, Gheorghe ; DAVIDESCU, Corneliu-Mircea ; ILIESCU, Smaranda ; PLESU, Nicoleta ; PASCARIU, Aurelia ; ZHENGPU ZHANG</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c303t-574f1dac067ffb20edb8d3ca450853891189b6f00585797fb0afdad9cc9f567e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Aldehydes</topic><topic>Applied sciences</topic><topic>Benzaldehyde</topic><topic>Chemical modifications</topic><topic>Chemical reactions</topic><topic>Chemical reactions and properties</topic><topic>Copolymers</topic><topic>Divinylbenzene</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers</topic><topic>Statistical methods</topic><topic>Styrenes</topic><topic>Tetrahydrofuran</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>POPA, Adriana</creatorcontrib><creatorcontrib>ILIA, Gheorghe</creatorcontrib><creatorcontrib>DAVIDESCU, Corneliu-Mircea</creatorcontrib><creatorcontrib>ILIESCU, Smaranda</creatorcontrib><creatorcontrib>PLESU, Nicoleta</creatorcontrib><creatorcontrib>PASCARIU, Aurelia</creatorcontrib><creatorcontrib>ZHENGPU ZHANG</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>POPA, Adriana</au><au>ILIA, Gheorghe</au><au>DAVIDESCU, Corneliu-Mircea</au><au>ILIESCU, Smaranda</au><au>PLESU, Nicoleta</au><au>PASCARIU, Aurelia</au><au>ZHENGPU ZHANG</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Wittig-horner reactions on styrene-divinylbenzene supports with benzaldehyde side-groups</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><date>2006-06-01</date><risdate>2006</risdate><volume>57</volume><issue>2</issue><spage>189</spage><epage>197</epage><pages>189-197</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><coden>POBUDR</coden><abstract>SummaryA styrene-divinylbenzene copolymer functionalized with aldehyde was prepared under phase transfer catalyzed (PTC) conditions. A statistical method for the calculation of the degree of functionalization with aldehyde groups is proposed. The degree of functionalization with aldehyde groups is relatively high.Styrene-divinylbenzene polymers functionalized with benzaldehyde groups were used in Wittig-Horner reaction, in order to introduce double bonds on polymers. The reactions were carried out using PTC method, solid-liquid-solid (s-l-s) (K2CO3, tetrahydrofuran, tetraethylammonium iodide) system. Phase transfer catalyzed reactions are often more easily and cheaply carried out than conventional method and they are therefore of particular interest.</abstract><cop>Heidelberg</cop><cop>Berlin</cop><cop>New York, NY</cop><pub>Springer</pub><doi>10.1007/s00289-006-0553-z</doi><tpages>9</tpages></addata></record> |
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| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2006-06, Vol.57 (2), p.189-197 |
| issn | 0170-0839 1436-2449 |
| language | eng |
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| source | Springer Link |
| subjects | Aldehydes Applied sciences Benzaldehyde Chemical modifications Chemical reactions Chemical reactions and properties Copolymers Divinylbenzene Exact sciences and technology Organic polymers Physicochemistry of polymers Polymers Statistical methods Styrenes Tetrahydrofuran |
| title | Wittig-horner reactions on styrene-divinylbenzene supports with benzaldehyde side-groups |
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