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Luminescence Behavior of Polynuclear Alkynylcopper(I) Phosphines

A series of soluble trinuclear and tetranuclear copper(I) complexes containing μ3-ηl acetylides , and have been synthesized and shown to exhibit rich photoluminescent behavior at room temperature. The electrochemistry of the trinuclear Cu(I) acetylide complexes and the excited-state redox properties...

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Bibliographic Details
Published in:Journal of cluster science 1999-03, Vol.10 (1), p.37-69
Main Authors: Yam, Vivian Wing-Wah, Fung, Wendy Kit-Mai, Cheung, Kung-Kai
Format: Article
Language:English
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Summary:A series of soluble trinuclear and tetranuclear copper(I) complexes containing μ3-ηl acetylides , and have been synthesized and shown to exhibit rich photoluminescent behavior at room temperature. The electrochemistry of the trinuclear Cu(I) acetylide complexes and the excited-state redox properties of have been investigated. The X-ray crystal structures of and have been determined.
ISSN:1040-7278
1572-8862
DOI:10.1023/A:1022600600818