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Luminescence Behavior of Polynuclear Alkynylcopper(I) Phosphines
A series of soluble trinuclear and tetranuclear copper(I) complexes containing μ3-ηl acetylides , and have been synthesized and shown to exhibit rich photoluminescent behavior at room temperature. The electrochemistry of the trinuclear Cu(I) acetylide complexes and the excited-state redox properties...
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Published in: | Journal of cluster science 1999-03, Vol.10 (1), p.37-69 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
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Summary: | A series of soluble trinuclear and tetranuclear copper(I) complexes containing μ3-ηl acetylides , and have been synthesized and shown to exhibit rich photoluminescent behavior at room temperature. The electrochemistry of the trinuclear Cu(I) acetylide complexes and the excited-state redox properties of have been investigated. The X-ray crystal structures of and have been determined. |
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ISSN: | 1040-7278 1572-8862 |
DOI: | 10.1023/A:1022600600818 |