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Enhancement of Luminescence Mechanisms in Structural, Morphological, and Catalytic Properties of Undoped CuCr2O4 and Mn-Doped CuCr2O4

In this work pure CuCr 2 O 4 and Mn-doped CuCr 2 O 4 nanoparticles were prepared using Microwave combustion process. The phase analysis of the prepared samples is investigated using X-Ray Diffraction technique and an decrease in particle size observed from ∼37 to ∼26 nm with rise in Mn doping concen...

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Bibliographic Details
Published in:Journal of cluster science 2023-05, Vol.34 (3), p.1527-1534
Main Authors: Sankudevan, P., Sakthivel, R. V., Prakasam, A., Al-Enizi, Abdullah M., Ubaidullah, Mohd, Pandit, Bidhan, Dash, Chandra Sekhar, Revathi, S., Roniboss, A., Sundararajan, M.
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Language:English
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Summary:In this work pure CuCr 2 O 4 and Mn-doped CuCr 2 O 4 nanoparticles were prepared using Microwave combustion process. The phase analysis of the prepared samples is investigated using X-Ray Diffraction technique and an decrease in particle size observed from ∼37 to ∼26 nm with rise in Mn doping concentration. Further optical data revealed the presence of multiple Mn-related optical centres . Morphological studies revealed the prepared samples exhibited irregular plate-shaped agglomerates. Furthermore, the antibacterial performance of undoped CuCr 2 O 4 and Mn-doped CuCr 2 O 4 samples are investigated. At 500 °C, the electrical conductivity for the CuCr 2 O 4 and Mn-doped CuCr 2 O 4 samples were found to be 0.98 × 10 −2 S/cm and 2.13 × 10 −2 S/cm respectively. The activation energy of the pristine CuCr 2 O 4 and Mn-doped CuCr 2 O 4 samples was found to be 0.87 eV and 0.69 eV respectively.
ISSN:1040-7278
1572-8862
DOI:10.1007/s10876-022-02328-0