Magnetic molecular materials with paramagnetic lanthanide ions

The diverse magnetic properties of lanthanide-based magnetic molecular materials are introduced in the following organization.First,the general aspects of magnetic molecular materials and electronic states of lanthanide ions are introduced.Then the structures and magnetic properties are described an...

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Bibliographic Details
Published in:Science China. Chemistry 2009-11, Vol.52 (11), p.1739-1758
Main Authors: Wang, BingWu, Jiang, ShangDa, Wang, XiuTeng, Gao, Song
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
compound
coordination
coupling
Electron states
lanthanide
magnet
magnetic
Magnetic induction
Magnetic properties
Magnetic relaxation
ordering
relaxation
single-chain
single-ion
single-molecule
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Description
Summary:The diverse magnetic properties of lanthanide-based magnetic molecular materials are introduced in the following organization.First,the general aspects of magnetic molecular materials and electronic states of lanthanide ions are introduced.Then the structures and magnetic properties are described and analyzed for molecules with one lanthanide ion,4f-4f,4f-3d and 4f-p magnetic coupling interactions.In each section,magnetic coupling,magnetic ordering and magnetic relaxation phenomenon are briefly reviewed using some examples.Finally,some possibilities of developing magnetic molecular materials containing lanthanide ions are discussed in the outlook part.
ISSN:1674-7291
1006-9291
1869-1870
1862-2771
DOI:10.1007/s11426-009-0275-9