Ultrasmall Pd nanoclusters： facile synthesis and versatile catalytic application

A simple and efficient method for the synthesis of ultrasmall Pd nanoclusters（NCs） has been developed. The as-obtained Pd NCs displayed uniform size with an average diameter of 1.8±0.2 nm. The ultrasmall Pd NCs and carbon nanotubes（CNTs）-supported Pd NCs also showed outstanding catalytic activity fo...

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Bibliographic Details
Published in:Science China. Chemistry 2015-03, Vol.58 (3), p.467-472
Main Authors: Xiang, Ji, Chong, Hanbao, Tang, Jia, Feng, Li, Zhou, Bin, Fu, Fangyu, Wang, Xin, Li, Peng, Zhu, Manzhou
Format: Article
Language:English
Subjects:
Carbon nanotubes
Catalytic activity
Chemical reactions
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Nanoclusters
Nitrobenzene
Suzuki偶联反应
催化应用
平均直径
简便合成
纳米团簇
超小型
通用
钯
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Summary:A simple and efficient method for the synthesis of ultrasmall Pd nanoclusters（NCs） has been developed. The as-obtained Pd NCs displayed uniform size with an average diameter of 1.8±0.2 nm. The ultrasmall Pd NCs and carbon nanotubes（CNTs）-supported Pd NCs also showed outstanding catalytic activity for nitrobenzene reduction and Suzuki coupling reactions. Notably, the reactions were conducted under mild conditions with high yield and selectivity.
ISSN:1674-7291
1869-1870
DOI:10.1007/s11426-014-5171-2