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An anthraquinone-based Cu(I) cyclic trinuclear complex for photo-catalyzing C-C coupling reactions
Development of transition metal-based photocatalysts with low cost, strong visible light absorption, and high efficiency is a long-stand pursuit for advanced organic synthesis, yet remains highly challenging. In this article, an anthraquinone-based copper(I) cyclic trinuclear complex ( 1 ) was desig...
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| Published in: | Science China. Chemistry 2023-12, Vol.66 (12), p.3525-3531 |
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| Main Authors: | , , , , , , |
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| cites | cdi_FETCH-LOGICAL-c316t-afd56597657049eb977dce37ec050150ab831b44db699cff2043ec72ff7ecc5f3 |
| container_end_page | 3531 |
| container_issue | 12 |
| container_start_page | 3525 |
| container_title | Science China. Chemistry |
| container_volume | 66 |
| creator | Wang, Yu-Mei Mo, Kai-Ming Luo, Xiao Xia, Ri-Qin Song, Jing-Yi Ning, Guo-Hong Li, Dan |
| description | Development of transition metal-based photocatalysts with low cost, strong visible light absorption, and high efficiency is a long-stand pursuit for advanced organic synthesis, yet remains highly challenging. In this article, an anthraquinone-based copper(I) cyclic trinuclear complex (
1
) was designed and it featured strong visible light absorption, high charge separation efficiency and photochemical properties. Complex
1
as a heterogeneous photocatalyst can efficiently catalyze homo-coupling of terminal alkynes and denitrification-oxidative coupling reaction between hydrazinopyridine and terminal alkynes with excellent yield (up to 99%), broad substrate tolerance (27 examples) and superior reusability (up to 10 cycles without loss of performance) under mild conditions. |
| doi_str_mv | 10.1007/s11426-023-1777-y |
| format | article |
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1
) was designed and it featured strong visible light absorption, high charge separation efficiency and photochemical properties. Complex
1
as a heterogeneous photocatalyst can efficiently catalyze homo-coupling of terminal alkynes and denitrification-oxidative coupling reaction between hydrazinopyridine and terminal alkynes with excellent yield (up to 99%), broad substrate tolerance (27 examples) and superior reusability (up to 10 cycles without loss of performance) under mild conditions.</description><identifier>ISSN: 1674-7291</identifier><identifier>EISSN: 1869-1870</identifier><identifier>DOI: 10.1007/s11426-023-1777-y</identifier><language>eng</language><publisher>Beijing: Science China Press</publisher><subject>Alkynes ; Anthraquinones ; Charge efficiency ; Chemical reactions ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Copper ; Coupling ; Crystals ; Efficiency ; Electromagnetic absorption ; Extinction ; Ligands ; Light ; NMR ; Nuclear magnetic resonance ; Photocatalysis ; Photocatalysts ; Solar energy ; Substrates ; Transition metals</subject><ispartof>Science China. Chemistry, 2023-12, Vol.66 (12), p.3525-3531</ispartof><rights>Science China Press 2023</rights><rights>Science China Press 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-afd56597657049eb977dce37ec050150ab831b44db699cff2043ec72ff7ecc5f3</citedby><cites>FETCH-LOGICAL-c316t-afd56597657049eb977dce37ec050150ab831b44db699cff2043ec72ff7ecc5f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wang, Yu-Mei</creatorcontrib><creatorcontrib>Mo, Kai-Ming</creatorcontrib><creatorcontrib>Luo, Xiao</creatorcontrib><creatorcontrib>Xia, Ri-Qin</creatorcontrib><creatorcontrib>Song, Jing-Yi</creatorcontrib><creatorcontrib>Ning, Guo-Hong</creatorcontrib><creatorcontrib>Li, Dan</creatorcontrib><title>An anthraquinone-based Cu(I) cyclic trinuclear complex for photo-catalyzing C-C coupling reactions</title><title>Science China. Chemistry</title><addtitle>Sci. China Chem</addtitle><description>Development of transition metal-based photocatalysts with low cost, strong visible light absorption, and high efficiency is a long-stand pursuit for advanced organic synthesis, yet remains highly challenging. In this article, an anthraquinone-based copper(I) cyclic trinuclear complex (
1
) was designed and it featured strong visible light absorption, high charge separation efficiency and photochemical properties. Complex
1
as a heterogeneous photocatalyst can efficiently catalyze homo-coupling of terminal alkynes and denitrification-oxidative coupling reaction between hydrazinopyridine and terminal alkynes with excellent yield (up to 99%), broad substrate tolerance (27 examples) and superior reusability (up to 10 cycles without loss of performance) under mild conditions.</description><subject>Alkynes</subject><subject>Anthraquinones</subject><subject>Charge efficiency</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Copper</subject><subject>Coupling</subject><subject>Crystals</subject><subject>Efficiency</subject><subject>Electromagnetic absorption</subject><subject>Extinction</subject><subject>Ligands</subject><subject>Light</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Solar energy</subject><subject>Substrates</subject><subject>Transition metals</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhoMouKz7A7wFvOghmo82aY9L8WNhwYueQ5omu126STdpwfrrzVLBk3OZGXjed5gXgFuCHwnG4ikSklGOMGWICCHQdAEWpOAlIoXAl2nmIkOCluQarGI84FSMYSryBajXDio37IM6ja3zzqBaRdPAarzfPEA96a7VcAitG3VnVIDaH_vOfEHrA-z3fvBIq0F103frdrBCVQLGvjsvwSg9tN7FG3BlVRfN6rcvwefL80f1hrbvr5tqvUWaET4gZZuc56XgucBZaepSiEYbJozGOSY5VnXBSJ1lTc3LUltLccaMFtTahOjcsiW4m3374E-jiYM8-DG4dFKm1wtORMFposhM6eBjDMbKPrRHFSZJsDynKec0ZUpTntOUU9LQWRMT63Ym_Dn_L_oB0yF4mw</recordid><startdate>20231201</startdate><enddate>20231201</enddate><creator>Wang, Yu-Mei</creator><creator>Mo, Kai-Ming</creator><creator>Luo, Xiao</creator><creator>Xia, Ri-Qin</creator><creator>Song, Jing-Yi</creator><creator>Ning, Guo-Hong</creator><creator>Li, Dan</creator><general>Science China Press</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20231201</creationdate><title>An anthraquinone-based Cu(I) cyclic trinuclear complex for photo-catalyzing C-C coupling reactions</title><author>Wang, Yu-Mei ; Mo, Kai-Ming ; Luo, Xiao ; Xia, Ri-Qin ; Song, Jing-Yi ; Ning, Guo-Hong ; Li, Dan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-afd56597657049eb977dce37ec050150ab831b44db699cff2043ec72ff7ecc5f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Alkynes</topic><topic>Anthraquinones</topic><topic>Charge efficiency</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Copper</topic><topic>Coupling</topic><topic>Crystals</topic><topic>Efficiency</topic><topic>Electromagnetic absorption</topic><topic>Extinction</topic><topic>Ligands</topic><topic>Light</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><topic>Solar energy</topic><topic>Substrates</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Yu-Mei</creatorcontrib><creatorcontrib>Mo, Kai-Ming</creatorcontrib><creatorcontrib>Luo, Xiao</creatorcontrib><creatorcontrib>Xia, Ri-Qin</creatorcontrib><creatorcontrib>Song, Jing-Yi</creatorcontrib><creatorcontrib>Ning, Guo-Hong</creatorcontrib><creatorcontrib>Li, Dan</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Databases</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Science Journals</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Science China. Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Yu-Mei</au><au>Mo, Kai-Ming</au><au>Luo, Xiao</au><au>Xia, Ri-Qin</au><au>Song, Jing-Yi</au><au>Ning, Guo-Hong</au><au>Li, Dan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An anthraquinone-based Cu(I) cyclic trinuclear complex for photo-catalyzing C-C coupling reactions</atitle><jtitle>Science China. Chemistry</jtitle><stitle>Sci. China Chem</stitle><date>2023-12-01</date><risdate>2023</risdate><volume>66</volume><issue>12</issue><spage>3525</spage><epage>3531</epage><pages>3525-3531</pages><issn>1674-7291</issn><eissn>1869-1870</eissn><abstract>Development of transition metal-based photocatalysts with low cost, strong visible light absorption, and high efficiency is a long-stand pursuit for advanced organic synthesis, yet remains highly challenging. In this article, an anthraquinone-based copper(I) cyclic trinuclear complex (
1
) was designed and it featured strong visible light absorption, high charge separation efficiency and photochemical properties. Complex
1
as a heterogeneous photocatalyst can efficiently catalyze homo-coupling of terminal alkynes and denitrification-oxidative coupling reaction between hydrazinopyridine and terminal alkynes with excellent yield (up to 99%), broad substrate tolerance (27 examples) and superior reusability (up to 10 cycles without loss of performance) under mild conditions.</abstract><cop>Beijing</cop><pub>Science China Press</pub><doi>10.1007/s11426-023-1777-y</doi><tpages>7</tpages></addata></record> |
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| ispartof | Science China. Chemistry, 2023-12, Vol.66 (12), p.3525-3531 |
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| language | eng |
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| source | Springer Link |
| subjects | Alkynes Anthraquinones Charge efficiency Chemical reactions Chemistry Chemistry and Materials Science Chemistry/Food Science Copper Coupling Crystals Efficiency Electromagnetic absorption Extinction Ligands Light NMR Nuclear magnetic resonance Photocatalysis Photocatalysts Solar energy Substrates Transition metals |
| title | An anthraquinone-based Cu(I) cyclic trinuclear complex for photo-catalyzing C-C coupling reactions |
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