Selective diesel production from syngas over non-noble metal catalyst via a novel hydrogenolysis mechanism

Finite petroleum reserves and stringent environmental regulations stimulate the development of alternative fuels that are economically viable and clean. The diesel fuel （C10-20 hydrocarbons） derived from syngas by Fischer- Tropsch synthesis （FTS） is a promising choice, as it has the merits of low su...

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Bibliographic Details
Published in:Science China. Chemistry 2015-06, Vol.58 (6), p.971-972
Main Author: Qiao, Minghua
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Highlights
Hydrogenolysis
Noble metals
Synthesis gas
合成气
替代燃料
机制
柴油燃料
氢解
生产
非贵金属催化剂
高十六烷值
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Summary:Finite petroleum reserves and stringent environmental regulations stimulate the development of alternative fuels that are economically viable and clean. The diesel fuel （C10-20 hydrocarbons） derived from syngas by Fischer- Tropsch synthesis （FTS） is a promising choice, as it has the merits of low sulfur and aronaatic contents, reduced NO, and particulate emissions, and high cetane number. Howev- er, the Anderson-Schulz-Flory （ASF） distribution imposes severe limitation on the selectivity towards diesel of only 39% over conventional FTS catalysts.
ISSN:1674-7291
1869-1870
DOI:10.1007/s11426-015-5424-8