Selected trace element concentrations in run-of-mine coal, discard, and coal product, and environmental implications

• Published in: Journal of the South African Institute of Mining and Metallurgy 2023-12, Vol.123 (12), p.573-577
• Main Authors: Mashishi, R.M., Okonkwo, O.J., Malehase, T.
• Format: Article
• Language: English
• Subjects: Cadmium; Coal mines; Lead; Marketability; Mass spectrometry; Mercury (metal); Trace elements
• ISSN: 2225-6253; 0038-223X; 2411-9717
• DOI: 10.17159/2411-9717/3114/2023

The concentrations of selected trace elements (As, Cd, Hg, and Pb in run-of-mine (ROM) coal, discard, and coal product were investigated to assess the efficiency of beneficiation in reducing trace element concentrations and ascertain any implications regarding environmental compliance to regulatory frameworks. Samples were collected from a colliery in Mpumalanga Province twice a month for a period of 24 months. The samples were ashed to approximately 0.21 mm, then digested in a mixture of 70% HNO3 and 40% HF and analysed using inductively coupled plasma-mass spectrometry (ICP-MS). Except for Pb, the mean concentration of all elements decreased from the ROM stage to the coal product stage. The order in which trace elements occurred from the highest to lowest throughout the production chain was Pb>As>Hg>Cd. With the exception of Cd, the mean trace element concentrations in the discard were above the total concentration threshold (TCT) set for landfill disposal. The As, Hg, and Cd concentrations in the product were well below the thresholds for all land uses. However, Pb concentrations in the product coal were above legal limits, which is of concern with regard to environmental compliance and the performance and marketability of the product.