Photoredox Suzuki coupling using alkyl boronic acids and esters

Herein, we report a novel methodology for the one-step synthesis of olefins via a transition metal-free pathway. The key step involved photo-induced deborylative radical initiation of an activated boronate complex followed by chemoselective vinylation, allylation and alkynylation in a one-pot manner...

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Bibliographic Details
Published in:Organic chemistry frontiers an international journal of organic chemistry 2024-01, Vol.11 (3), p.854-863
Main Authors: Das, Kanak Kanti, Mahato, Somenath, Ghorai, Debraj, Dey, Sutapa, Panda, Santanu
Format: Article
Language:English
Subjects:
Alkenes
Allyl compounds
Chemical reactions
Esters
Transition metals
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Summary:Herein, we report a novel methodology for the one-step synthesis of olefins via a transition metal-free pathway. The key step involved photo-induced deborylative radical initiation of an activated boronate complex followed by chemoselective vinylation, allylation and alkynylation in a one-pot manner.
ISSN:2052-4110
2052-4110
DOI:10.1039/d3qo01838e