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Role of MnO in manganese–borate binary glass systems: a study on structure and thermal properties
Structural and thermal properties of x MnO - ( 100 - x ) B 2 O 3 (where x = 40 , 50 and 60 mol%) glass samples have been investigated with the employment of various techniques. Fourier transform infrared spectroscopy results revealed the influence of MnO on glass matrix. Decrease of B–O bond-related...
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| Published in: | Bulletin of materials science 2017-09, Vol.40 (5), p.933-938 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c359t-f48d4aebd3d0743f63666e67b782c45ba23c01fcb2eaff316546a0af6b9d5d5d3 |
| container_end_page | 938 |
| container_issue | 5 |
| container_start_page | 933 |
| container_title | Bulletin of materials science |
| container_volume | 40 |
| creator | Lewandowski, T Łapiński, M Walas, M Prześniak-Welenc, M Wicikowski, L |
| description | Structural and thermal properties of
x
MnO
-
(
100
-
x
)
B
2
O
3
(where
x
=
40
, 50 and 60 mol%) glass samples have been investigated with the employment of various techniques. Fourier transform infrared spectroscopy results revealed the influence of MnO on glass matrix. Decrease of B–O bond-related band intensities has been observed. MnO addition was found to introduce broken [
BO
2
O
-
]
n
chains. Differential scanning calorimetry (DSC) measurements presented decreasing
T
g
that indicates depolymerization of glass matrix in the considered compositional range. Moreover, thermal stability (TS) parameter has been evaluated using the DSC technique. It slightly decreased with MnO content. X-ray photoelectron spectroscopy results provided the evidence for
Mn
2
+
and
Mn
3
+
presence. Multiplet splitting, close to that of MnO, has been observed. It has been concluded that most of the manganese ions existed in the divalent state. Photoluminescence study revealed that manganese ions are tetragonally co-ordinated in a glassy matrix. |
| doi_str_mv | 10.1007/s12034-017-1455-4 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2919971880</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2919971880</sourcerecordid><originalsourceid>FETCH-LOGICAL-c359t-f48d4aebd3d0743f63666e67b782c45ba23c01fcb2eaff316546a0af6b9d5d5d3</originalsourceid><addsrcrecordid>eNp1kM1KxDAQx4MouK4-gLeA52jSpEnjTRa_QFkQPYe0naxd2nRN0sPefAff0CcxywqeZA4zh_8H80PonNFLRqm6iqygXBDKFGGiLIk4QDOqFSdKSn2Y76KkRCiqjtFJjGtKmRaCzVDzMvaAR4ef_RJ3Hg_Wr6yHCN-fX_UYbAJcd96GLV71NkYctzHBEK-xxTFN7RaPPh9hatIUAFvf4vQOYbA93oRxAyF1EE_RkbN9hLPfPUdvd7eviwfytLx_XNw8kYaXOhEnqlZYqFveUiW4k1xKCVLVqioaUda24A1lrqkLsM5xJkshLbVO1rot8_A5utjn5uqPCWIy63EKPleaQjOtFasqmlVsr2rCGGMAZzahG_KHhlGzY2n2LE1maXYsjcieYu-JWetXEP6S_zf9AKteeRo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2919971880</pqid></control><display><type>article</type><title>Role of MnO in manganese–borate binary glass systems: a study on structure and thermal properties</title><source>Indian Academy of Sciences</source><source>Springer Link</source><creator>Lewandowski, T ; Łapiński, M ; Walas, M ; Prześniak-Welenc, M ; Wicikowski, L</creator><creatorcontrib>Lewandowski, T ; Łapiński, M ; Walas, M ; Prześniak-Welenc, M ; Wicikowski, L</creatorcontrib><description>Structural and thermal properties of
x
MnO
-
(
100
-
x
)
B
2
O
3
(where
x
=
40
, 50 and 60 mol%) glass samples have been investigated with the employment of various techniques. Fourier transform infrared spectroscopy results revealed the influence of MnO on glass matrix. Decrease of B–O bond-related band intensities has been observed. MnO addition was found to introduce broken [
BO
2
O
-
]
n
chains. Differential scanning calorimetry (DSC) measurements presented decreasing
T
g
that indicates depolymerization of glass matrix in the considered compositional range. Moreover, thermal stability (TS) parameter has been evaluated using the DSC technique. It slightly decreased with MnO content. X-ray photoelectron spectroscopy results provided the evidence for
Mn
2
+
and
Mn
3
+
presence. Multiplet splitting, close to that of MnO, has been observed. It has been concluded that most of the manganese ions existed in the divalent state. Photoluminescence study revealed that manganese ions are tetragonally co-ordinated in a glassy matrix.</description><identifier>ISSN: 0250-4707</identifier><identifier>EISSN: 0973-7669</identifier><identifier>DOI: 10.1007/s12034-017-1455-4</identifier><language>eng</language><publisher>Bangalore, India: Indian Academy of Sciences</publisher><subject>Boron oxides ; Chemistry and Materials Science ; Depolymerization ; Differential scanning calorimetry ; Electrons ; Employment ; Engineering ; Fine structure ; Fourier transforms ; Grain size ; Infrared spectroscopy ; Manganese ions ; Manganese oxides ; Materials Science ; Optics ; Photoelectrons ; Photoluminescence ; Spectrum analysis ; Stability analysis ; Temperature ; Thermal stability ; Thermodynamic properties ; X ray photoelectron spectroscopy</subject><ispartof>Bulletin of materials science, 2017-09, Vol.40 (5), p.933-938</ispartof><rights>Indian Academy of Sciences 2017</rights><rights>Indian Academy of Sciences 2017.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-f48d4aebd3d0743f63666e67b782c45ba23c01fcb2eaff316546a0af6b9d5d5d3</citedby><cites>FETCH-LOGICAL-c359t-f48d4aebd3d0743f63666e67b782c45ba23c01fcb2eaff316546a0af6b9d5d5d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Lewandowski, T</creatorcontrib><creatorcontrib>Łapiński, M</creatorcontrib><creatorcontrib>Walas, M</creatorcontrib><creatorcontrib>Prześniak-Welenc, M</creatorcontrib><creatorcontrib>Wicikowski, L</creatorcontrib><title>Role of MnO in manganese–borate binary glass systems: a study on structure and thermal properties</title><title>Bulletin of materials science</title><addtitle>Bull Mater Sci</addtitle><description>Structural and thermal properties of
x
MnO
-
(
100
-
x
)
B
2
O
3
(where
x
=
40
, 50 and 60 mol%) glass samples have been investigated with the employment of various techniques. Fourier transform infrared spectroscopy results revealed the influence of MnO on glass matrix. Decrease of B–O bond-related band intensities has been observed. MnO addition was found to introduce broken [
BO
2
O
-
]
n
chains. Differential scanning calorimetry (DSC) measurements presented decreasing
T
g
that indicates depolymerization of glass matrix in the considered compositional range. Moreover, thermal stability (TS) parameter has been evaluated using the DSC technique. It slightly decreased with MnO content. X-ray photoelectron spectroscopy results provided the evidence for
Mn
2
+
and
Mn
3
+
presence. Multiplet splitting, close to that of MnO, has been observed. It has been concluded that most of the manganese ions existed in the divalent state. Photoluminescence study revealed that manganese ions are tetragonally co-ordinated in a glassy matrix.</description><subject>Boron oxides</subject><subject>Chemistry and Materials Science</subject><subject>Depolymerization</subject><subject>Differential scanning calorimetry</subject><subject>Electrons</subject><subject>Employment</subject><subject>Engineering</subject><subject>Fine structure</subject><subject>Fourier transforms</subject><subject>Grain size</subject><subject>Infrared spectroscopy</subject><subject>Manganese ions</subject><subject>Manganese oxides</subject><subject>Materials Science</subject><subject>Optics</subject><subject>Photoelectrons</subject><subject>Photoluminescence</subject><subject>Spectrum analysis</subject><subject>Stability analysis</subject><subject>Temperature</subject><subject>Thermal stability</subject><subject>Thermodynamic properties</subject><subject>X ray photoelectron spectroscopy</subject><issn>0250-4707</issn><issn>0973-7669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kM1KxDAQx4MouK4-gLeA52jSpEnjTRa_QFkQPYe0naxd2nRN0sPefAff0CcxywqeZA4zh_8H80PonNFLRqm6iqygXBDKFGGiLIk4QDOqFSdKSn2Y76KkRCiqjtFJjGtKmRaCzVDzMvaAR4ef_RJ3Hg_Wr6yHCN-fX_UYbAJcd96GLV71NkYctzHBEK-xxTFN7RaPPh9hatIUAFvf4vQOYbA93oRxAyF1EE_RkbN9hLPfPUdvd7eviwfytLx_XNw8kYaXOhEnqlZYqFveUiW4k1xKCVLVqioaUda24A1lrqkLsM5xJkshLbVO1rot8_A5utjn5uqPCWIy63EKPleaQjOtFasqmlVsr2rCGGMAZzahG_KHhlGzY2n2LE1maXYsjcieYu-JWetXEP6S_zf9AKteeRo</recordid><startdate>20170901</startdate><enddate>20170901</enddate><creator>Lewandowski, T</creator><creator>Łapiński, M</creator><creator>Walas, M</creator><creator>Prześniak-Welenc, M</creator><creator>Wicikowski, L</creator><general>Indian Academy of Sciences</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20170901</creationdate><title>Role of MnO in manganese–borate binary glass systems: a study on structure and thermal properties</title><author>Lewandowski, T ; Łapiński, M ; Walas, M ; Prześniak-Welenc, M ; Wicikowski, L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-f48d4aebd3d0743f63666e67b782c45ba23c01fcb2eaff316546a0af6b9d5d5d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Boron oxides</topic><topic>Chemistry and Materials Science</topic><topic>Depolymerization</topic><topic>Differential scanning calorimetry</topic><topic>Electrons</topic><topic>Employment</topic><topic>Engineering</topic><topic>Fine structure</topic><topic>Fourier transforms</topic><topic>Grain size</topic><topic>Infrared spectroscopy</topic><topic>Manganese ions</topic><topic>Manganese oxides</topic><topic>Materials Science</topic><topic>Optics</topic><topic>Photoelectrons</topic><topic>Photoluminescence</topic><topic>Spectrum analysis</topic><topic>Stability analysis</topic><topic>Temperature</topic><topic>Thermal stability</topic><topic>Thermodynamic properties</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lewandowski, T</creatorcontrib><creatorcontrib>Łapiński, M</creatorcontrib><creatorcontrib>Walas, M</creatorcontrib><creatorcontrib>Prześniak-Welenc, M</creatorcontrib><creatorcontrib>Wicikowski, L</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Bulletin of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lewandowski, T</au><au>Łapiński, M</au><au>Walas, M</au><au>Prześniak-Welenc, M</au><au>Wicikowski, L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Role of MnO in manganese–borate binary glass systems: a study on structure and thermal properties</atitle><jtitle>Bulletin of materials science</jtitle><stitle>Bull Mater Sci</stitle><date>2017-09-01</date><risdate>2017</risdate><volume>40</volume><issue>5</issue><spage>933</spage><epage>938</epage><pages>933-938</pages><issn>0250-4707</issn><eissn>0973-7669</eissn><abstract>Structural and thermal properties of
x
MnO
-
(
100
-
x
)
B
2
O
3
(where
x
=
40
, 50 and 60 mol%) glass samples have been investigated with the employment of various techniques. Fourier transform infrared spectroscopy results revealed the influence of MnO on glass matrix. Decrease of B–O bond-related band intensities has been observed. MnO addition was found to introduce broken [
BO
2
O
-
]
n
chains. Differential scanning calorimetry (DSC) measurements presented decreasing
T
g
that indicates depolymerization of glass matrix in the considered compositional range. Moreover, thermal stability (TS) parameter has been evaluated using the DSC technique. It slightly decreased with MnO content. X-ray photoelectron spectroscopy results provided the evidence for
Mn
2
+
and
Mn
3
+
presence. Multiplet splitting, close to that of MnO, has been observed. It has been concluded that most of the manganese ions existed in the divalent state. Photoluminescence study revealed that manganese ions are tetragonally co-ordinated in a glassy matrix.</abstract><cop>Bangalore, India</cop><pub>Indian Academy of Sciences</pub><doi>10.1007/s12034-017-1455-4</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0250-4707 |
| ispartof | Bulletin of materials science, 2017-09, Vol.40 (5), p.933-938 |
| issn | 0250-4707 0973-7669 |
| language | eng |
| recordid | cdi_proquest_journals_2919971880 |
| source | Indian Academy of Sciences; Springer Link |
| subjects | Boron oxides Chemistry and Materials Science Depolymerization Differential scanning calorimetry Electrons Employment Engineering Fine structure Fourier transforms Grain size Infrared spectroscopy Manganese ions Manganese oxides Materials Science Optics Photoelectrons Photoluminescence Spectrum analysis Stability analysis Temperature Thermal stability Thermodynamic properties X ray photoelectron spectroscopy |
| title | Role of MnO in manganese–borate binary glass systems: a study on structure and thermal properties |
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