Revealing the Removal Mechanism of Vanadium Addition on Nitrogen Pores in 30Cr15Mo1N High‐Nitrogen Steel Ingot

• Published in: Steel research international 2024-02, Vol.95 (2), p.n/a
• Main Authors: Zhu, Hong-Chun, Ni, Zhuo-Wen, Li, Hua-Bing, He, Zhi-Yu, Li, Bin, Feng, Hao, Jiang, Zhou-Hua
• Format: Article
• Language: English
• Subjects: Bubbles; Casting; Diameters; high-nitrogen steels; Ingots; Nitrogen; nitrogen pores; Nucleation; Solidification; Stainless steels; Statistical analysis; Thermodynamic models; Vanadium; vanadium addition
• ISSN: 1611-3683; 1869-344X
• DOI: 10.1002/srin.202300550

The removal mechanism of vanadium addition on nitrogen pores in 30Cr15Mo1N ingot is systematically investigated through statistical analysis and theoretical calculation. The nitrogen solubility is obtained by the thermodynamic model, and the nitrogen content is obtained by combining the ProCAST software and the C–K model. Then, according to the formula of critical nucleation radius and growth rate of nitrogen bubbles, the variation of critical nucleation radius and growth rate of nitrogen bubbles with different vanadium contents is calculated. As the vanadium content increases, the number and mean area of nitrogen pores decrease. In comparison to the 0 V ingot, the number of nitrogen pores decreases in the 0.2 V ingot, but there is an increase in the number of large‐sized nitrogen pores (>3000 μm in diameter). When the vanadium content increases to 0.4, the nitrogen pores are completely removed. The results demonstrate that increasing vanadium content can remove nitrogen pores. Since the solidification mode remains unchanged with increasing vanadium content, increasing the vanadium content cannot remove nitrogen pores by changing the solidification mode of the 30Cr15Mo1N ingots. Therefore, increasing the vanadium content removes the nitrogen pores mainly by inhibiting the nucleation of nitrogen bubbles and promoting nitrogen bubble overflow in 30Cr15Mo1N ingots. Since the solidification mode remains unchanged with increasing vanadium content, increasing the vanadium content cannot remove nitrogen pores by changing the solidification mode of the 30Cr15Mo1N ingots. Therefore, increasing the vanadium content removes the nitrogen pores mainly by inhibiting the nucleation of nitrogen bubbles and promoting nitrogen bubble overflow in 30Cr15Mo1N ingots.