Ag-based coordination polymer-enhanced photocatalytic degradation of ciprofloxacin and nitrophenol

• Published in: Dalton transactions : an international journal of inorganic chemistry 2024-02, Vol.53 (8), p.3797-387
• Main Authors: Ma, Zhihu, Song, Xiaoming, Li, Zhaoyu, Ren, Yixia, Wang, Jijiang, Liang, Yucang
• Format: Article
• Language: English
• Subjects: Catalytic activity; Charge transfer; Chemical synthesis; Coordination compounds; Coordination polymers; Density functional theory; Ligands; Light irradiation; Liquid chromatography; Mass spectrometry; Molecular structure; Nitrates; Nitrogen atoms; Nitrophenol; Photocatalysis; Photodegradation; Silver nitrate; Single crystals; Structural stability; Transition metals
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d3dt03727d

Transition-metal coordination complexes have attracted wide attention in molecular chemistry, but their applications still confront a tremendous challenge. Herein, a novel silver coordination polymer with a formula of {[Ag 9 (TIPA) 6 ](NO 3 ) 9 ·12H 2 O} n (Ag-TIPA) was prepared by a solvothermal reaction of silver nitrate with triangular tris(4-imidazolylphenyl)amine (TIPA). The crystalline molecular structure was determined by single-crystal X-ray diffraction, which showed that each Ag( i ) was coordinated with two nitrogen atoms of TIPA ligands. Such Ag-TIPA was used as a catalyst for the photodegradation of ciprofloxacin and 4-nitrophenol under UV-visible light irradiation. The results exhibited excellent photocatalytic performance and reusability due to high structure stability in an acidic, neutral and alkaline environment. The experimental findings and density functional theory calculations revealed that metal-ligand charge transfer in Ag-TIPA extended the absorption range of light and improved the charge transfer properties of TIPA. To further understand the photodegradation process, the intermediates were predicted and analysed through electrostatic potential, orbital weighted dual descriptor, and liquid chromatography-mass spectrometry techniques. Based on these findings, a possible degradation mechanism was proposed. This study provides new insights into the design and synthesis of Ag-based coordination polymers with novel structures, excellent catalytic activity, and good durability. A novel Ag coordination polymer (Ag-TIPA) was rationally designed, successfully prepared and used for the photodegradation of ciprofloxacin and nitrophenol, showing excellent photocatalytic performance and high reusability.