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“2+1B” Tricarbonyl Complexes of Technetium-99m and Rhenium with N,N '-Bidentate Ligands and Methyl 2-(Decylthio)-6-isocyanohexanoate
“2+1 B ” tricarbonyl complexes of the general formula [M(CO) 3 (N^N)CN(CH 2 ) 4 CH(COOMe)SC 10 H 21 ]-ClO 4 , where M = 99 m Tc or Re, N^N = 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO) 3 (N^N)(MeOH)]ClO 4 with methyl 2-(decylthio)-6-isocyanohexa...
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Published in: | Radiochemistry (New York, N.Y.) N.Y.), 2023-12, Vol.65 (6), p.672-679 |
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Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites |
Online Access: | Get full text |
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Summary: | “2+1
B
” tricarbonyl complexes of the general formula [M(CO)
3
(N^N)CN(CH
2
)
4
CH(COOMe)SC
10
H
21
]-ClO
4
, where M =
99
m
Tc or Re, N^N = 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)
3
(N^N)(MeOH)]ClO
4
with methyl 2-(decylthio)-6-isocyanohexanoate in methanol. The rhenium complexes were isolated and characterized by
1
H NMR and IR spectroscopy. The formation of technetium-99
m
complexes was confirmed by HPLC. The lipophilicity of the technetium complexes was measured. |
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ISSN: | 1066-3622 1608-3288 |
DOI: | 10.1134/S1066362223060085 |