Cooling Damage Characterization and Chemical-Enhanced Oil Recovery in Low-Permeable and High-Waxy Oil Reservoirs

• Published in: Processes 2024-02, Vol.12 (2), p.421
• Main Authors: Li, Xuanran, Zhao, Lun, Fei, Ruijie, Wang, Jincai, Liu, Shanglin, Li, Minghui, Han, Shujun, Zhou, Fujian, Yuan, Shuai
• Format: Article
• Language: English
• Subjects: Chemical damage; Chemical precipitation; Cooling; Crude oil; Crystals; Deposition; Dewaxing; Differential scanning calorimetry; Drainage; Emulsions; Enhanced oil recovery; Liquid injection; Magnetic resonance imaging; Measurement techniques; Medical imaging; Nanoemulsions; NMR; Nuclear magnetic resonance; Oil fields; Permeability; Petroleum mining; Phase transitions; Physical properties; Pores; Reservoirs; Rheological properties; Scanning electron microscopy; Surface tension; Temperature; Thermal analysis; Viscosity; Waxes; Wettability
• ISSN: 2227-9717; 2227-9717
• DOI: 10.3390/pr12020421

The well productivity of high-waxy reservoirs is highly influenced by temperature changes. A decrease in temperature can cause the precipitation of wax from the crude oil, leading to a decrease in the formation’s drainage capacity and a drop in oil production. In this study, the wax precipitation of crude oil is characterized by rheological properties tests and differential scanning calorimetry (DSC) thermal analysis. The wax damage characteristics of cores and the relative permeability curves at different temperatures were investigated through coreflood experiments. Furthermore, nanoemulsion is selected as a chemical agent for injection fluid. The nuclear magnetic resonance (NMR) scanning technique is used to investigate the effects of oil recovery enhancement at different pores by increasing temperature and adding nanoemulsion. By comparing the changes in T2 spectra and the distribution pattern of residual oil before and after liquid injection, the results have shown that both increasing temperature and adding nanoemulsion have a significant effect on oil recovery. The improvement of micropores is less pronounced compared to macropores. The produced oil mainly comes from the large pores. When the temperature is lower than the crude oil dewaxing point temperature, there is a serious dewaxing plugging phenomenon in the pores. Additionally, by observing the pattern of residual oil distribution at the end of the NMR online drive, it is hereby classified into wax deposition retention type, weak water washing retention type, and immobilized type, each with its own distinct characteristics. Wettability alteration and interfacial tension reduction can help to improve the drainage capacity of high-wax oil reservoirs, which is the main mechanism of nanoemulsion for enhanced oil recovery. These findings are highly valuable for enhancing the comprehension of the impact of highly waxed crude oils on drainage capacity and the ultimate oil recovery rate, particularly in relation to wax precipitation deposition.