Electron–Nuclear Alignment in Radicals Formed by Photochemical Decomposition of Molecules

Calculations of electron–nuclear alignment (CIDEP multiplet effect) in radicals formed as a result of the photochemical decomposition of molecules have been performed. There is a mutual ordering of spins in the radicals: the electron and nuclear spins in the radical are oriented parallel or antipara...

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Bibliographic Details
Published in:High energy chemistry 2023-12, Vol.57 (Suppl 3), p.S460-S463
Main Author: Purtov, P. A.
Format: Article
Language:English
Subjects:
Alignment
Chemistry
Chemistry and Materials Science
Decomposition
Electron spin
Fine structure
Kinematics
Mathematical analysis
Physical Chemistry
Radicals
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Summary:Calculations of electron–nuclear alignment (CIDEP multiplet effect) in radicals formed as a result of the photochemical decomposition of molecules have been performed. There is a mutual ordering of spins in the radicals: the electron and nuclear spins in the radical are oriented parallel or antiparallel. The populations of stationary states of radicals in weak magnetic fields have been calculated in the framework of the kinematic approach.
ISSN:0018-1439
1608-3148
DOI:10.1134/S001814392309014X