Three-dimensional porous CoNiO2@reduced graphene oxide nanosheet arrays/nickel foam as a highly efficient bifunctional electrocatalyst for overall water splitting

• Published in: Tungsten 2020-12, Vol.2 (4), p.390-402
• Main Authors: Pan, Zhi-Yi, Tang, Zheng, Zhan, Yong-Zhong, Sun, Dan
• Format: Article
• Language: English
• Subjects: Chemistry and Materials Science; Current density; Electrocatalysts; Electrodes; Electrolytes; Energy; Ethanol; Graphene; Heterostructures; Hydrogen evolution reactions; Materials Engineering; Materials Science; Metal foams; Metal oxides; Metallic Materials; Nanosheets; Nickel; Nuclear Chemistry; Original Paper; Oxygen evolution reactions; Particle and Nuclear Physics; Radiation; Spectrum analysis; Stainless steel; Synergistic effect; Voltammetry; Water splitting
• ISSN: 2661-8028; 2661-8036
• DOI: 10.1007/s42864-020-00065-3

It is crucial to develop high-performance and cost-effective bifunctional electrocatalysts for both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) toward overall water splitting. Herein, a unique heterostructure of reduced graphene oxide (rGO) and CoNiO 2 nanosheets directly grown on nickel foam (NF) were successfully fabricated and applied as a kind of highly efficient bifunctional electrocatalyst. The optimum CoNiO 2 @rGO/NF electrode exhibits excellent electrocatalytic OER performance with an overpotential of only 272 mV to drive a current density of 100 mA·cm −2 , and HER performance with an overpotential of 126 mV to achieve a current density of 10 mA·cm −2 . Meanwhile, the electrodes also display outstanding long-term stability for OER and HER with negligible activity and morphology degradation after at least 40 h testing. Furthermore, when employed as both cathode and anode for overall water splitting, CoNiO 2 @rGO/NF electrode only requires 1.56 V at 10 mA·cm −2 and operates stably for over 40 h, which is among the best performing Co-based and Ni-based non-precious metal electrocatalysts. Detailed characterizations reveal that the extraordinary electrocatalytic performance should be attributed to the synergistic effect of the unique heterostructure of CoNiO 2 nanosheets and rGO for increasing the electrode conductivity and integrity, ultrasmall primary particle size for providing larger electrode/electrolyte contact area and abundant active sites, and three-dimensional (3D) conductive networks for facilitating the electrochemical reaction.