Loading…
Polymorphic cerium-based Prussian blue derivatives with in situ growing CNT/Co heterojunctions for enhanced microwave absorption via polarization and magnetization
In this paper, the structure evolution of cerium cobaltohexanoate (Ce[Co(CN) 6 ], Ce-Co Prussian blue analog (PBA)) has been realized by solvent catalysis at room temperature. The hexagonal bipyramidal microcrystals of Ce-Co PBA can be gradually transformed into dendrites by different proportions of...
Saved in:
| Published in: | Nano research 2024-03, Vol.17 (3), p.2050-2060 |
|---|---|
| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c316t-5c2708a2db3a4fca259897ee9cc83cb245a15aa958d58dbc1cbe2bb17d8c69413 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c316t-5c2708a2db3a4fca259897ee9cc83cb245a15aa958d58dbc1cbe2bb17d8c69413 |
| container_end_page | 2060 |
| container_issue | 3 |
| container_start_page | 2050 |
| container_title | Nano research |
| container_volume | 17 |
| creator | Zhou, Jixi Huang, Xinmeng Lan, Di Cheng, Yuhang Xue, Fengyi Jia, Chenyu Wu, Guanglei Jia, Zirui |
| description | In this paper, the structure evolution of cerium cobaltohexanoate (Ce[Co(CN)
6
], Ce-Co Prussian blue analog (PBA)) has been realized by solvent catalysis at room temperature. The hexagonal bipyramidal microcrystals of Ce-Co PBA can be gradually transformed into dendrites by different proportions of ethanol (EtOH) and water. At the same time, the porous dendrites CeO
2
/Co@carbon nanotub (CNT) with oxygen-rich vacancies (OVs) can be obtained by annealing Ce-Co PBA at 700 °C. The microstructure study shows that carbon nanotubes will be catalyzed after annealing at high temperature, and the cobalt metal particles encapsulated in carbon nanotubes will be anchored in the matrix, regulating the impedance matching and multi-polarization suppression of the material, and its unique structure, vacancies, and strong interface effect make the material exhibit excellent electromagnetic wave (EMW) absorption performance. When the matching thickness is 2.5 mm, the minimum reflection loss (RL
min
) of the composite is −51.68 dB, and the effective absorption bandwidth (RL < −10 dB) is 7.76 GHz. These results show that the prepared CeO
2
/Co@CNT composite has excellent EMW absorption properties. It is expected to be a candidate material for EMW absorption. |
| doi_str_mv | 10.1007/s12274-023-6216-7 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2938257106</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2938257106</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-5c2708a2db3a4fca259897ee9cc83cb245a15aa958d58dbc1cbe2bb17d8c69413</originalsourceid><addsrcrecordid>eNp1kc1KAzEUhQdRsFYfwF3A9dgk85ulFP-gaBd1HW4ymZmUaTImMy36Or6oqa24MlxIuPc75xJOFF0TfEswLmaeUFqkMaZJnFOSx8VJNCGMlTEO5_T3TWh6Hl14v8Y4UGk5ib6WtvvYWNe3WiKpnB43sQCvKrR0o_caDBLdqFAVRlsY9FZ5tNNDi7RBXg8japzdadOg-ctqNreoVYNydj0aOWhrPKqtQ8q0YGSw3GgZaNgqBMKHnXsEbTWg3nbg9Cf8NMAEEhqjhmPnMjqrofPq6nhPo7eH-9X8KV68Pj7P7xaxTEg-xJmkBS6BViKBtJZAM1ayQikmZZlIQdMMSAbAsrIKJSSRQlEhSFGVMmcpSabRzcG3d_Z9VH7gazs6E1ZyypKSZgXBeaDIgQp_8d6pmvdOb8B9cIL5Pgt-yIKHLPg-C14EDT1ofGBNo9yf8_-ibwMPkaQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2938257106</pqid></control><display><type>article</type><title>Polymorphic cerium-based Prussian blue derivatives with in situ growing CNT/Co heterojunctions for enhanced microwave absorption via polarization and magnetization</title><source>Springer Nature</source><creator>Zhou, Jixi ; Huang, Xinmeng ; Lan, Di ; Cheng, Yuhang ; Xue, Fengyi ; Jia, Chenyu ; Wu, Guanglei ; Jia, Zirui</creator><creatorcontrib>Zhou, Jixi ; Huang, Xinmeng ; Lan, Di ; Cheng, Yuhang ; Xue, Fengyi ; Jia, Chenyu ; Wu, Guanglei ; Jia, Zirui</creatorcontrib><description>In this paper, the structure evolution of cerium cobaltohexanoate (Ce[Co(CN)
6
], Ce-Co Prussian blue analog (PBA)) has been realized by solvent catalysis at room temperature. The hexagonal bipyramidal microcrystals of Ce-Co PBA can be gradually transformed into dendrites by different proportions of ethanol (EtOH) and water. At the same time, the porous dendrites CeO
2
/Co@carbon nanotub (CNT) with oxygen-rich vacancies (OVs) can be obtained by annealing Ce-Co PBA at 700 °C. The microstructure study shows that carbon nanotubes will be catalyzed after annealing at high temperature, and the cobalt metal particles encapsulated in carbon nanotubes will be anchored in the matrix, regulating the impedance matching and multi-polarization suppression of the material, and its unique structure, vacancies, and strong interface effect make the material exhibit excellent electromagnetic wave (EMW) absorption performance. When the matching thickness is 2.5 mm, the minimum reflection loss (RL
min
) of the composite is −51.68 dB, and the effective absorption bandwidth (RL < −10 dB) is 7.76 GHz. These results show that the prepared CeO
2
/Co@CNT composite has excellent EMW absorption properties. It is expected to be a candidate material for EMW absorption.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-023-6216-7</identifier><language>eng</language><publisher>Beijing: Tsinghua University Press</publisher><subject>Absorption ; Annealing ; Atomic/Molecular Structure and Spectra ; Biomedicine ; Biotechnology ; Carbon ; Carbon nanotubes ; Catalysis ; Cerium ; Cerium oxides ; Chemistry and Materials Science ; Cobalt ; Condensed Matter Physics ; Dendrites ; Electromagnetic radiation ; EM Wave Functional Materials ; Ethanol ; Heterojunctions ; High temperature ; Impedance matching ; Materials Science ; Materials selection ; Metal particles ; Microcrystals ; Microwave absorption ; Nanotechnology ; Nanotubes ; Pigments ; Polarization ; Research Article ; Room temperature</subject><ispartof>Nano research, 2024-03, Vol.17 (3), p.2050-2060</ispartof><rights>Tsinghua University Press 2023</rights><rights>Tsinghua University Press 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-5c2708a2db3a4fca259897ee9cc83cb245a15aa958d58dbc1cbe2bb17d8c69413</citedby><cites>FETCH-LOGICAL-c316t-5c2708a2db3a4fca259897ee9cc83cb245a15aa958d58dbc1cbe2bb17d8c69413</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Zhou, Jixi</creatorcontrib><creatorcontrib>Huang, Xinmeng</creatorcontrib><creatorcontrib>Lan, Di</creatorcontrib><creatorcontrib>Cheng, Yuhang</creatorcontrib><creatorcontrib>Xue, Fengyi</creatorcontrib><creatorcontrib>Jia, Chenyu</creatorcontrib><creatorcontrib>Wu, Guanglei</creatorcontrib><creatorcontrib>Jia, Zirui</creatorcontrib><title>Polymorphic cerium-based Prussian blue derivatives with in situ growing CNT/Co heterojunctions for enhanced microwave absorption via polarization and magnetization</title><title>Nano research</title><addtitle>Nano Res</addtitle><description>In this paper, the structure evolution of cerium cobaltohexanoate (Ce[Co(CN)
6
], Ce-Co Prussian blue analog (PBA)) has been realized by solvent catalysis at room temperature. The hexagonal bipyramidal microcrystals of Ce-Co PBA can be gradually transformed into dendrites by different proportions of ethanol (EtOH) and water. At the same time, the porous dendrites CeO
2
/Co@carbon nanotub (CNT) with oxygen-rich vacancies (OVs) can be obtained by annealing Ce-Co PBA at 700 °C. The microstructure study shows that carbon nanotubes will be catalyzed after annealing at high temperature, and the cobalt metal particles encapsulated in carbon nanotubes will be anchored in the matrix, regulating the impedance matching and multi-polarization suppression of the material, and its unique structure, vacancies, and strong interface effect make the material exhibit excellent electromagnetic wave (EMW) absorption performance. When the matching thickness is 2.5 mm, the minimum reflection loss (RL
min
) of the composite is −51.68 dB, and the effective absorption bandwidth (RL < −10 dB) is 7.76 GHz. These results show that the prepared CeO
2
/Co@CNT composite has excellent EMW absorption properties. It is expected to be a candidate material for EMW absorption.</description><subject>Absorption</subject><subject>Annealing</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Biomedicine</subject><subject>Biotechnology</subject><subject>Carbon</subject><subject>Carbon nanotubes</subject><subject>Catalysis</subject><subject>Cerium</subject><subject>Cerium oxides</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt</subject><subject>Condensed Matter Physics</subject><subject>Dendrites</subject><subject>Electromagnetic radiation</subject><subject>EM Wave Functional Materials</subject><subject>Ethanol</subject><subject>Heterojunctions</subject><subject>High temperature</subject><subject>Impedance matching</subject><subject>Materials Science</subject><subject>Materials selection</subject><subject>Metal particles</subject><subject>Microcrystals</subject><subject>Microwave absorption</subject><subject>Nanotechnology</subject><subject>Nanotubes</subject><subject>Pigments</subject><subject>Polarization</subject><subject>Research Article</subject><subject>Room temperature</subject><issn>1998-0124</issn><issn>1998-0000</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kc1KAzEUhQdRsFYfwF3A9dgk85ulFP-gaBd1HW4ymZmUaTImMy36Or6oqa24MlxIuPc75xJOFF0TfEswLmaeUFqkMaZJnFOSx8VJNCGMlTEO5_T3TWh6Hl14v8Y4UGk5ib6WtvvYWNe3WiKpnB43sQCvKrR0o_caDBLdqFAVRlsY9FZ5tNNDi7RBXg8japzdadOg-ctqNreoVYNydj0aOWhrPKqtQ8q0YGSw3GgZaNgqBMKHnXsEbTWg3nbg9Cf8NMAEEhqjhmPnMjqrofPq6nhPo7eH-9X8KV68Pj7P7xaxTEg-xJmkBS6BViKBtJZAM1ayQikmZZlIQdMMSAbAsrIKJSSRQlEhSFGVMmcpSabRzcG3d_Z9VH7gazs6E1ZyypKSZgXBeaDIgQp_8d6pmvdOb8B9cIL5Pgt-yIKHLPg-C14EDT1ofGBNo9yf8_-ibwMPkaQ</recordid><startdate>20240301</startdate><enddate>20240301</enddate><creator>Zhou, Jixi</creator><creator>Huang, Xinmeng</creator><creator>Lan, Di</creator><creator>Cheng, Yuhang</creator><creator>Xue, Fengyi</creator><creator>Jia, Chenyu</creator><creator>Wu, Guanglei</creator><creator>Jia, Zirui</creator><general>Tsinghua University Press</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>K9.</scope><scope>L7M</scope><scope>P64</scope></search><sort><creationdate>20240301</creationdate><title>Polymorphic cerium-based Prussian blue derivatives with in situ growing CNT/Co heterojunctions for enhanced microwave absorption via polarization and magnetization</title><author>Zhou, Jixi ; Huang, Xinmeng ; Lan, Di ; Cheng, Yuhang ; Xue, Fengyi ; Jia, Chenyu ; Wu, Guanglei ; Jia, Zirui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-5c2708a2db3a4fca259897ee9cc83cb245a15aa958d58dbc1cbe2bb17d8c69413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Absorption</topic><topic>Annealing</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Biomedicine</topic><topic>Biotechnology</topic><topic>Carbon</topic><topic>Carbon nanotubes</topic><topic>Catalysis</topic><topic>Cerium</topic><topic>Cerium oxides</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt</topic><topic>Condensed Matter Physics</topic><topic>Dendrites</topic><topic>Electromagnetic radiation</topic><topic>EM Wave Functional Materials</topic><topic>Ethanol</topic><topic>Heterojunctions</topic><topic>High temperature</topic><topic>Impedance matching</topic><topic>Materials Science</topic><topic>Materials selection</topic><topic>Metal particles</topic><topic>Microcrystals</topic><topic>Microwave absorption</topic><topic>Nanotechnology</topic><topic>Nanotubes</topic><topic>Pigments</topic><topic>Polarization</topic><topic>Research Article</topic><topic>Room temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Jixi</creatorcontrib><creatorcontrib>Huang, Xinmeng</creatorcontrib><creatorcontrib>Lan, Di</creatorcontrib><creatorcontrib>Cheng, Yuhang</creatorcontrib><creatorcontrib>Xue, Fengyi</creatorcontrib><creatorcontrib>Jia, Chenyu</creatorcontrib><creatorcontrib>Wu, Guanglei</creatorcontrib><creatorcontrib>Jia, Zirui</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Nano research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Jixi</au><au>Huang, Xinmeng</au><au>Lan, Di</au><au>Cheng, Yuhang</au><au>Xue, Fengyi</au><au>Jia, Chenyu</au><au>Wu, Guanglei</au><au>Jia, Zirui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymorphic cerium-based Prussian blue derivatives with in situ growing CNT/Co heterojunctions for enhanced microwave absorption via polarization and magnetization</atitle><jtitle>Nano research</jtitle><stitle>Nano Res</stitle><date>2024-03-01</date><risdate>2024</risdate><volume>17</volume><issue>3</issue><spage>2050</spage><epage>2060</epage><pages>2050-2060</pages><issn>1998-0124</issn><eissn>1998-0000</eissn><abstract>In this paper, the structure evolution of cerium cobaltohexanoate (Ce[Co(CN)
6
], Ce-Co Prussian blue analog (PBA)) has been realized by solvent catalysis at room temperature. The hexagonal bipyramidal microcrystals of Ce-Co PBA can be gradually transformed into dendrites by different proportions of ethanol (EtOH) and water. At the same time, the porous dendrites CeO
2
/Co@carbon nanotub (CNT) with oxygen-rich vacancies (OVs) can be obtained by annealing Ce-Co PBA at 700 °C. The microstructure study shows that carbon nanotubes will be catalyzed after annealing at high temperature, and the cobalt metal particles encapsulated in carbon nanotubes will be anchored in the matrix, regulating the impedance matching and multi-polarization suppression of the material, and its unique structure, vacancies, and strong interface effect make the material exhibit excellent electromagnetic wave (EMW) absorption performance. When the matching thickness is 2.5 mm, the minimum reflection loss (RL
min
) of the composite is −51.68 dB, and the effective absorption bandwidth (RL < −10 dB) is 7.76 GHz. These results show that the prepared CeO
2
/Co@CNT composite has excellent EMW absorption properties. It is expected to be a candidate material for EMW absorption.</abstract><cop>Beijing</cop><pub>Tsinghua University Press</pub><doi>10.1007/s12274-023-6216-7</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1998-0124 |
| ispartof | Nano research, 2024-03, Vol.17 (3), p.2050-2060 |
| issn | 1998-0124 1998-0000 |
| language | eng |
| recordid | cdi_proquest_journals_2938257106 |
| source | Springer Nature |
| subjects | Absorption Annealing Atomic/Molecular Structure and Spectra Biomedicine Biotechnology Carbon Carbon nanotubes Catalysis Cerium Cerium oxides Chemistry and Materials Science Cobalt Condensed Matter Physics Dendrites Electromagnetic radiation EM Wave Functional Materials Ethanol Heterojunctions High temperature Impedance matching Materials Science Materials selection Metal particles Microcrystals Microwave absorption Nanotechnology Nanotubes Pigments Polarization Research Article Room temperature |
| title | Polymorphic cerium-based Prussian blue derivatives with in situ growing CNT/Co heterojunctions for enhanced microwave absorption via polarization and magnetization |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T17%3A22%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Polymorphic%20cerium-based%20Prussian%20blue%20derivatives%20with%20in%20situ%20growing%20CNT/Co%20heterojunctions%20for%20enhanced%20microwave%20absorption%20via%20polarization%20and%20magnetization&rft.jtitle=Nano%20research&rft.au=Zhou,%20Jixi&rft.date=2024-03-01&rft.volume=17&rft.issue=3&rft.spage=2050&rft.epage=2060&rft.pages=2050-2060&rft.issn=1998-0124&rft.eissn=1998-0000&rft_id=info:doi/10.1007/s12274-023-6216-7&rft_dat=%3Cproquest_cross%3E2938257106%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c316t-5c2708a2db3a4fca259897ee9cc83cb245a15aa958d58dbc1cbe2bb17d8c69413%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2938257106&rft_id=info:pmid/&rfr_iscdi=true |