4,5-Diiodo-1- H -imidazole-derived linker ligand and Cu( i ) and Co( ii ) coordination polymers based thereupon

A new iodine-rich imidazole derivative 1,4-bis(4,5-diiodo-1 H -imidazol-1-yl)butane (bimbI 4 , 1) features multiple I⋯I interactions in the solid state. Using 1 as a precursor, we prepared 1D and 2D coordination polymers of Co( ii ) and Cu(I) – {[Co(bimbI 4 )Cl 2 ]·1.5DMF} n (2) and {[Cu 2 I 2 (bimb...

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Bibliographic Details
Published in:CrystEngComm 2024-03, Vol.26 (11), p.1607-1612
Main Authors: Zaguzin, Alexander S., Zaitsev, Artem V., Korobeynikov, Nikita A., Novikov, Alexander S., Usoltsev, Andrey N., Fedin, Vladimir P., Adonin, Sergey A.
Format: Article
Language:English
Subjects:
Coordination polymers
Imidazole
Iodine
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Summary:A new iodine-rich imidazole derivative 1,4-bis(4,5-diiodo-1 H -imidazol-1-yl)butane (bimbI 4 , 1) features multiple I⋯I interactions in the solid state. Using 1 as a precursor, we prepared 1D and 2D coordination polymers of Co( ii ) and Cu(I) – {[Co(bimbI 4 )Cl 2 ]·1.5DMF} n (2) and {[Cu 2 I 2 (bimbI 4 )]} n (3), respectively, also featuring extended systems of halogen bonds within their structures.
ISSN:1466-8033
1466-8033
DOI:10.1039/D4CE00072B