Y1/6Yb5/6TaO4/8YSZ composite ceramics with enhanced mechanical and thermal properties

Ceramic thermal barrier coatings (TBCs) with high toughness and low thermal conductivity are important for developing aero engines with high thrust‐to‐weight ratio and thermal efficiency. In this work, the properties of tantalate Y1/6Yb5/6TaO4 (YYT) were optimized by introducing 8 wt.% yttria‐stabil...

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Bibliographic Details
Published in:Journal of the American Ceramic Society 2024-06, Vol.107 (6), p.3895-3909
Main Authors: Wang, Jiankun, Chen, Lin, Zhang, Luyang, Gan, Mengdi, Li, Baihui, Feng, Jing
Format: Article
Language:English
Subjects:
Ceramics
composite ceramics
Composite materials
Crystal defects
Heat conductivity
Heat transfer
High thrust
Intergranular fracture
Microcracks
Modulus of elasticity
Plasma sintering
rare‐earth tantalates
Residual stress
Spark plasma sintering
Synthesis
TBCs
Thermal barrier coatings
Thermal conductivity
Thermal expansion
Thermodynamic efficiency
Thermodynamic properties
toughening mechanisms
Transgranular fracture
Yttrium oxide
Zirconium dioxide
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Summary:Ceramic thermal barrier coatings (TBCs) with high toughness and low thermal conductivity are important for developing aero engines with high thrust‐to‐weight ratio and thermal efficiency. In this work, the properties of tantalate Y1/6Yb5/6TaO4 (YYT) were optimized by introducing 8 wt.% yttria‐stabilized zirconia (8YSZ), synthesized using spark plasma sintering, as a second‐phase ceramic. The highest toughness (3.57 MPa m1/2) of the YYT/8YSZ composite ceramics was due to multiple toughening mechanisms. The underlying mechanisms of these processes were revealed based on the microstructures and residual stress of the YYT/8YSZ composite ceramics. A shift from an intergranular fracture to a transgranular fracture was caused by the difference between soft‐grain YYT and hard‐grain 8YSZ, which consumed the fracture energy. Furthermore, the formation of microcracks, crack deflection, bridging, and branching were analyzed based on the differences in Young's moduli and thermal expansion coefficients of YYT and 8YSZ. Internal defects and weak connections between the YYT and 8YSZ grains reduced the thermal conductivity of the composites until it reached its lowest value at 1.4 W m−1 K−1. The studied toughening mechanisms could be applied to various composites. Moreover, herein, we provide a new strategy to design and synthesize TBCs with enhanced performance.
ISSN:0002-7820
1551-2916
DOI:10.1111/jace.19687