The Influence of SnO2 and Noble Metals on the Properties of TiO2 for Environmental Sustainability

In order to find solutions to current worldwide environmental problems, it is crucial to develop sustainable nanomaterials, ideally with multifunctional properties. Considering this, novel TiO2-SnO2@NMs (noble metals: Au and Ag) composites, for use as sustainable nanomaterials, were successfully pre...

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Bibliographic Details
Published in:Sustainability 2024-04, Vol.16 (7), p.2904
Main Authors: Goncearenco, Evghenii, Morjan, Iuliana P., Fleaca, Claudiu, Dutu, Elena, Criveanu, Anca, Viespe, Cristian, Galca, Aurelian Catalin, Maraloiu, Adrian Valentin, Stan, Miruna S., Fort, Carmen Ioana, Scarisoreanu, Monica
Format: Article
Language:English
Subjects:
Accident prevention
Composite materials
Cytotoxicity
Dyes
Environmental impact
Gases
Lasers
Light
Metal oxides
Nanomaterials
Nanoparticles
Photocatalysis
Photodegradation
Sensors
Skin
Tin
Toxicity
Water pollution
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Summary:In order to find solutions to current worldwide environmental problems, it is crucial to develop sustainable nanomaterials, ideally with multifunctional properties. Considering this, novel TiO2-SnO2@NMs (noble metals: Au and Ag) composites, for use as sustainable nanomaterials, were successfully prepared via a two-step synthesis process consisting of laser pyrolysis followed by the chemical impregnation of the collected materials with noble metals. The addition of SnO2 favors the transformation of TiO2 from a mixture with a majority Anatase phase to one with a Rutile phase majority. With consideration for their level of environmental toxicity, the features of the synthesized nanomaterials were structurally, morphologically, and optically described and assessed for environmental protection applications as gas sensors and photocatalysts. In the case of the Surface Acoustic Wave sensor, based on a pure TiO2 nanopowder, a notable difference in the frequency shift was detected in comparison to the other examined sensors. All sensors responded to the CH4 concentrations tested (0.02–0.1%). On the other hand, when methyl orange was photodegraded under visible light, the results obtained using NMs for decoration revealed that the photocatalytic activity of TiO2-SnO2@NMs was significantly improved compared to the TiO2-SnO2 binary composite, which already has an enhanced photocatalytic activity, compared to pure TiO2. Overall, this work produces nanoparticles that exhibit better sensory and photocatalytic features, as well as higher levels of biocompatibility with skin cells, for use as eco-friendly nanomaterials for a sustainable future.
ISSN:2071-1050
2071-1050
DOI:10.3390/su16072904