Blue light-mediated carbene transfer reaction of thioesters with diazoesters: efficient synthesis of tetrasubstituted Z-enol esters

A novel and efficient metal-free, blue light-mediated carbene transfer reaction of thioesters with diazoesters has been achieved. This protocol produces a variety of tetrasubstituted Z-enol esters containing aryl sulfur groups in good yields under mild, convenient and catalyst-free conditions.

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Bibliographic Details
Published in:Organic chemistry frontiers an international journal of organic chemistry 2024-05, Vol.11 (10), p.2928-2933
Main Authors: Wang, Shuncheng, Zhang, Hua, Yang, Jin, Zhang, Dongfang, Xin-Ping, Hui
Format: Article
Language:English
Subjects:
Carbenes
Catalysts
Esters
Sulfur
Thioesters
Online Access:Get full text
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Description
Summary:A novel and efficient metal-free, blue light-mediated carbene transfer reaction of thioesters with diazoesters has been achieved. This protocol produces a variety of tetrasubstituted Z-enol esters containing aryl sulfur groups in good yields under mild, convenient and catalyst-free conditions.
ISSN:2052-4110
2052-4110
DOI:10.1039/d4qo00265b