Enhanced Ferromagnetism in Atomically Thin Oxides Achieved by Interfacial Reconstruction

• Published in: Advanced functional materials 2024-05, Vol.34 (22), p.n/a
• Main Authors: Yi, Di, Tang, Aihua, Kane, Margaret M., Xu, Liubin, Liu, Jingchun, Cheng, Zhiying, Klewe, Christoph, N'Diaye, Alpha T., Shafer, Padraic, Yu, Pu, Yu, Rong, Xu, Haixuan, Lin, Yuanhua, Nan, Cewen, Suzuki, Yuri
• Format: Article
• Language: English
• Subjects: 2D ferromagnetism; Curie temperature; Electrons; Ferromagnetic materials; Heterostructures; interface reconstruction; Magnetic anisotropy; Magnetic saturation; Monolayers; perpendicular magnetic anisotropy; Spintronics; Thickness; transition metal oxide; Transition metal oxides
• ISSN: 1616-301X; 1616-3028
• DOI: 10.1002/adfm.202313294

Discoveries of ferromagnetic materials with ultrathin thickness are of great importance for both fundamental science and technological applications. Transition metal oxides (TMOs) provide promising candidates in the context of next‐generation spintronics, despite the severe decay of ferromagnetism as the thickness reduces to the nanometer regime. Here, an efficient strategy to eliminate the magnetic dead layer in atomically thin oxides is presented, by using the epitaxial interface of 3d and 5d oxide monolayers that reconciles both strong exchange interaction and large uniaxial magnetic anisotropy. Combining multiple experimental methods, a ferromagnetic transition in an ultrathin oxide heterostructure comprised of only one La0.2Sr0.8MnO3 monolayer sandwiched by SrIrO3 monolayer (total thickness of three unit‐cells) is unambiguously demonstrated. Remarkably, a largely enhanced saturation magnetization (2 µB Mn−1) and Curie temperature (80 K) are observed for the single manganite monolayer, as compared to previously reported ferromagnetic monolayer oxides. The results demonstrate a general strategy for creating robust ferromagnetism in ultrathin TMOs, potentially enabling novel oxide spin‐orbitronic devices. This study reports a novel approach to eliminate the magnetic dead layer in atomically thin oxides, by using the epitaxial interface that reconciles both strong exchange interaction and large uniaxial magnetic anisotropy. A largely enhanced saturation magnetization (2 μB Mn−1) and Curie temperature (80 K) are observed for the single manganite monolayer when interfacing with 5d oxides.