Facile access to benzofuran-based bis-stilbene for organic laser dyes

A concise and efficient synthetic protocol for the synthesis of furan-based bis-stilbene derivatives (BPBFCz1) was described, which is a very promising organic laser dye. Starting with 4,4'-diethynylbiphenyl, BPBFCz1 was prepared with a total yield of 40% through a three-step classical reaction...

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Published in:Synthetic communications 2024-06, Vol.54 (11), p.927-934
Main Authors: Zheng, Ziyi, Bian, Guangling, Song, Ling
Format: Article
Language:English
Subjects:
benzofuran
bis-stilbene
Cross coupling
Crystal structure
Dyes
organic gain media
Organic laser dyes
Organic lasers
sonogashira coupling
Stilbene
Synthesis
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container_title Synthetic communications
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creator Zheng, Ziyi
Bian, Guangling
Song, Ling
description A concise and efficient synthetic protocol for the synthesis of furan-based bis-stilbene derivatives (BPBFCz1) was described, which is a very promising organic laser dye. Starting with 4,4'-diethynylbiphenyl, BPBFCz1 was prepared with a total yield of 40% through a three-step classical reaction of Sonogashira Coupling, intramolecular cyclization of 2-alkynyl phenol, and Buchwald Hartwig cross-coupling. The crystal structure of BPBFCz1 was presented for the first time. The synthesis strategy was applied to the synthesis of other three materials with similar structure and the yields of 28.6-36.6% were obtained.
doi_str_mv 10.1080/00397911.2024.2356632
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subjects benzofuran
bis-stilbene
Cross coupling
Crystal structure
Dyes
organic gain media
Organic laser dyes
Organic lasers
sonogashira coupling
Stilbene
Synthesis
title Facile access to benzofuran-based bis-stilbene for organic laser dyes
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