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Enhanced cycling performance of lithium-ion batteries with V2O5 as cathode by Co-doping for structural stability
The high capacity and cycling performance are important for the lithium-ion battery (LIB). V 2 O 5 is considered a good active material among various potential candidates due to its low cost, abundant availability, and high energy density, however, the disadvantage of lower cycling performance is di...
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| Published in: | Journal of applied electrochemistry 2024, Vol.54 (7), p.1473-1484 |
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| container_start_page | 1473 |
| container_title | Journal of applied electrochemistry |
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| creator | Yuan, Baohe Yuan, Xiang An, Zheng Zhang, Binger Luo, Shijun Chen, Lulu Liu, Xiansheng |
| description | The high capacity and cycling performance are important for the lithium-ion battery (LIB). V
2
O
5
is considered a good active material among various potential candidates due to its low cost, abundant availability, and high energy density, however, the disadvantage of lower cycling performance is difficult to solve due to structural instability during the charging and discharging process. Here, we prepared composite microspheres of Co-doped V
2
O
5
by a simple solvothermal method for solving structural instability. As the cathode material in LIBs, the V
2
O
5
-Co
0.1
composite microspheres exhibit a specific capacity of 171 mAhg
−1
at a current density of 0.08 Ag
−1
(except for the first cycle). After 10 cycles, the specific capacity of V
2
O
5
-Co
0.1
composite microspheres did not change, it exhibited better cycling stability. When the current density is increased to 0.1 Ag
−1
and 0.3 Ag
−1
, 241 mAhg
−1
and 200 mAhg
−1
specific capacities are obtained. Although the initial specific capacity of pure V
2
O
5
microspheres was higher than that of V
2
O
5
-Co
0.1
, its capacity retention after cycling was 86%, which was lower than that of V
2
O
5
-Co
0.1
. The reason for the enhanced stability of V
2
O
5
-Co
0.1
composite microspheres is that Co ions are fixed between the layered structures of V
2
O
5
, which increases the stability of the V
2
O
5
structure.
Graphical Abstract |
| doi_str_mv | 10.1007/s10800-023-02050-3 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3062886190</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3062886190</sourcerecordid><originalsourceid>FETCH-LOGICAL-c270t-1d8e2b5f739bded80262be89d62cd028817c67247999faf5c468a7428dc926853</originalsourceid><addsrcrecordid>eNp9kE1LxDAQhoMouK7-AU8Bz9FJ0o_kKMv6AcJeVLyFNEl3u3SbmrRI_71ZK3jzMMwwvO8zzIvQNYVbClDeRQoCgADjqSAHwk_QguYlI0JwcYoWAIwSIenHObqIcQ8AkhXZAvXrbqc74yw2k2mbbot7F2ofDscl9jVum2HXjAfS-A5XehhcaFzEX2mL39kmxzpio4edtw5XE155Yn1_xCQGjkMYzTAG3aZRV01iTZforNZtdFe_fYneHtavqyfysnl8Xt2_EMNKGAi1wrEqr0suK-usAFawyglpC2YsMCFoaYqSZaWUstZ1brJC6DJjwpr0mMj5Et3M3D74z9HFQe39GLp0UnEoEqCgEpKKzSoTfIzB1aoPzUGHSVFQx2TVnKxKyaqfZBVPJj6bYhJ3Wxf-0P-4vgE0g3wS</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3062886190</pqid></control><display><type>article</type><title>Enhanced cycling performance of lithium-ion batteries with V2O5 as cathode by Co-doping for structural stability</title><source>Springer Nature</source><creator>Yuan, Baohe ; Yuan, Xiang ; An, Zheng ; Zhang, Binger ; Luo, Shijun ; Chen, Lulu ; Liu, Xiansheng</creator><creatorcontrib>Yuan, Baohe ; Yuan, Xiang ; An, Zheng ; Zhang, Binger ; Luo, Shijun ; Chen, Lulu ; Liu, Xiansheng</creatorcontrib><description>The high capacity and cycling performance are important for the lithium-ion battery (LIB). V
2
O
5
is considered a good active material among various potential candidates due to its low cost, abundant availability, and high energy density, however, the disadvantage of lower cycling performance is difficult to solve due to structural instability during the charging and discharging process. Here, we prepared composite microspheres of Co-doped V
2
O
5
by a simple solvothermal method for solving structural instability. As the cathode material in LIBs, the V
2
O
5
-Co
0.1
composite microspheres exhibit a specific capacity of 171 mAhg
−1
at a current density of 0.08 Ag
−1
(except for the first cycle). After 10 cycles, the specific capacity of V
2
O
5
-Co
0.1
composite microspheres did not change, it exhibited better cycling stability. When the current density is increased to 0.1 Ag
−1
and 0.3 Ag
−1
, 241 mAhg
−1
and 200 mAhg
−1
specific capacities are obtained. Although the initial specific capacity of pure V
2
O
5
microspheres was higher than that of V
2
O
5
-Co
0.1
, its capacity retention after cycling was 86%, which was lower than that of V
2
O
5
-Co
0.1
. The reason for the enhanced stability of V
2
O
5
-Co
0.1
composite microspheres is that Co ions are fixed between the layered structures of V
2
O
5
, which increases the stability of the V
2
O
5
structure.
Graphical Abstract</description><identifier>ISSN: 0021-891X</identifier><identifier>EISSN: 1572-8838</identifier><identifier>DOI: 10.1007/s10800-023-02050-3</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Cathodes ; Chemistry ; Chemistry and Materials Science ; Current density ; Cycles ; Electrochemistry ; Electrode materials ; Industrial Chemistry/Chemical Engineering ; Lithium-ion batteries ; Microspheres ; Physical Chemistry ; Rechargeable batteries ; Research Article ; Structural stability ; Vanadium pentoxide</subject><ispartof>Journal of applied electrochemistry, 2024, Vol.54 (7), p.1473-1484</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-1d8e2b5f739bded80262be89d62cd028817c67247999faf5c468a7428dc926853</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Yuan, Baohe</creatorcontrib><creatorcontrib>Yuan, Xiang</creatorcontrib><creatorcontrib>An, Zheng</creatorcontrib><creatorcontrib>Zhang, Binger</creatorcontrib><creatorcontrib>Luo, Shijun</creatorcontrib><creatorcontrib>Chen, Lulu</creatorcontrib><creatorcontrib>Liu, Xiansheng</creatorcontrib><title>Enhanced cycling performance of lithium-ion batteries with V2O5 as cathode by Co-doping for structural stability</title><title>Journal of applied electrochemistry</title><addtitle>J Appl Electrochem</addtitle><description>The high capacity and cycling performance are important for the lithium-ion battery (LIB). V
2
O
5
is considered a good active material among various potential candidates due to its low cost, abundant availability, and high energy density, however, the disadvantage of lower cycling performance is difficult to solve due to structural instability during the charging and discharging process. Here, we prepared composite microspheres of Co-doped V
2
O
5
by a simple solvothermal method for solving structural instability. As the cathode material in LIBs, the V
2
O
5
-Co
0.1
composite microspheres exhibit a specific capacity of 171 mAhg
−1
at a current density of 0.08 Ag
−1
(except for the first cycle). After 10 cycles, the specific capacity of V
2
O
5
-Co
0.1
composite microspheres did not change, it exhibited better cycling stability. When the current density is increased to 0.1 Ag
−1
and 0.3 Ag
−1
, 241 mAhg
−1
and 200 mAhg
−1
specific capacities are obtained. Although the initial specific capacity of pure V
2
O
5
microspheres was higher than that of V
2
O
5
-Co
0.1
, its capacity retention after cycling was 86%, which was lower than that of V
2
O
5
-Co
0.1
. The reason for the enhanced stability of V
2
O
5
-Co
0.1
composite microspheres is that Co ions are fixed between the layered structures of V
2
O
5
, which increases the stability of the V
2
O
5
structure.
Graphical Abstract</description><subject>Cathodes</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Current density</subject><subject>Cycles</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Lithium-ion batteries</subject><subject>Microspheres</subject><subject>Physical Chemistry</subject><subject>Rechargeable batteries</subject><subject>Research Article</subject><subject>Structural stability</subject><subject>Vanadium pentoxide</subject><issn>0021-891X</issn><issn>1572-8838</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouK7-AU8Bz9FJ0o_kKMv6AcJeVLyFNEl3u3SbmrRI_71ZK3jzMMwwvO8zzIvQNYVbClDeRQoCgADjqSAHwk_QguYlI0JwcYoWAIwSIenHObqIcQ8AkhXZAvXrbqc74yw2k2mbbot7F2ofDscl9jVum2HXjAfS-A5XehhcaFzEX2mL39kmxzpio4edtw5XE155Yn1_xCQGjkMYzTAG3aZRV01iTZforNZtdFe_fYneHtavqyfysnl8Xt2_EMNKGAi1wrEqr0suK-usAFawyglpC2YsMCFoaYqSZaWUstZ1brJC6DJjwpr0mMj5Et3M3D74z9HFQe39GLp0UnEoEqCgEpKKzSoTfIzB1aoPzUGHSVFQx2TVnKxKyaqfZBVPJj6bYhJ3Wxf-0P-4vgE0g3wS</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Yuan, Baohe</creator><creator>Yuan, Xiang</creator><creator>An, Zheng</creator><creator>Zhang, Binger</creator><creator>Luo, Shijun</creator><creator>Chen, Lulu</creator><creator>Liu, Xiansheng</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2024</creationdate><title>Enhanced cycling performance of lithium-ion batteries with V2O5 as cathode by Co-doping for structural stability</title><author>Yuan, Baohe ; Yuan, Xiang ; An, Zheng ; Zhang, Binger ; Luo, Shijun ; Chen, Lulu ; Liu, Xiansheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-1d8e2b5f739bded80262be89d62cd028817c67247999faf5c468a7428dc926853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Cathodes</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Current density</topic><topic>Cycles</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Lithium-ion batteries</topic><topic>Microspheres</topic><topic>Physical Chemistry</topic><topic>Rechargeable batteries</topic><topic>Research Article</topic><topic>Structural stability</topic><topic>Vanadium pentoxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yuan, Baohe</creatorcontrib><creatorcontrib>Yuan, Xiang</creatorcontrib><creatorcontrib>An, Zheng</creatorcontrib><creatorcontrib>Zhang, Binger</creatorcontrib><creatorcontrib>Luo, Shijun</creatorcontrib><creatorcontrib>Chen, Lulu</creatorcontrib><creatorcontrib>Liu, Xiansheng</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of applied electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yuan, Baohe</au><au>Yuan, Xiang</au><au>An, Zheng</au><au>Zhang, Binger</au><au>Luo, Shijun</au><au>Chen, Lulu</au><au>Liu, Xiansheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced cycling performance of lithium-ion batteries with V2O5 as cathode by Co-doping for structural stability</atitle><jtitle>Journal of applied electrochemistry</jtitle><stitle>J Appl Electrochem</stitle><date>2024</date><risdate>2024</risdate><volume>54</volume><issue>7</issue><spage>1473</spage><epage>1484</epage><pages>1473-1484</pages><issn>0021-891X</issn><eissn>1572-8838</eissn><abstract>The high capacity and cycling performance are important for the lithium-ion battery (LIB). V
2
O
5
is considered a good active material among various potential candidates due to its low cost, abundant availability, and high energy density, however, the disadvantage of lower cycling performance is difficult to solve due to structural instability during the charging and discharging process. Here, we prepared composite microspheres of Co-doped V
2
O
5
by a simple solvothermal method for solving structural instability. As the cathode material in LIBs, the V
2
O
5
-Co
0.1
composite microspheres exhibit a specific capacity of 171 mAhg
−1
at a current density of 0.08 Ag
−1
(except for the first cycle). After 10 cycles, the specific capacity of V
2
O
5
-Co
0.1
composite microspheres did not change, it exhibited better cycling stability. When the current density is increased to 0.1 Ag
−1
and 0.3 Ag
−1
, 241 mAhg
−1
and 200 mAhg
−1
specific capacities are obtained. Although the initial specific capacity of pure V
2
O
5
microspheres was higher than that of V
2
O
5
-Co
0.1
, its capacity retention after cycling was 86%, which was lower than that of V
2
O
5
-Co
0.1
. The reason for the enhanced stability of V
2
O
5
-Co
0.1
composite microspheres is that Co ions are fixed between the layered structures of V
2
O
5
, which increases the stability of the V
2
O
5
structure.
Graphical Abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10800-023-02050-3</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-891X |
| ispartof | Journal of applied electrochemistry, 2024, Vol.54 (7), p.1473-1484 |
| issn | 0021-891X 1572-8838 |
| language | eng |
| recordid | cdi_proquest_journals_3062886190 |
| source | Springer Nature |
| subjects | Cathodes Chemistry Chemistry and Materials Science Current density Cycles Electrochemistry Electrode materials Industrial Chemistry/Chemical Engineering Lithium-ion batteries Microspheres Physical Chemistry Rechargeable batteries Research Article Structural stability Vanadium pentoxide |
| title | Enhanced cycling performance of lithium-ion batteries with V2O5 as cathode by Co-doping for structural stability |
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