Visible-light-promoted synthesis of α,α-difluoro-β-keto-thio(seleno)ethers from thio(seleno)sulfonates and difluoroenoxysilanes

A visible light-promoted strategy for arylthiodifluoromethylation of thiosulfonates and difluoroenoxysilanes has been developed. This protocol is characterized by its high efficiency and mild reaction conditions, offering a supplementary strategy for synthesis of α,α-difluoro-β-ketosthioethers.

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Bibliographic Details
Published in:Organic chemistry frontiers an international journal of organic chemistry 2024, Vol.11 (12), p.3364-3368
Main Authors: Yao, Shuang, Wang, Fei, Chen, Ying, Rao, Weidong, Shu-Su, Shen, Sheng, Daopeng, Shun-Yi, Wang
Format: Article
Language:English
Subjects:
Ethers
Sulfonates
Synthesis
Online Access:Get full text
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Description
Summary:A visible light-promoted strategy for arylthiodifluoromethylation of thiosulfonates and difluoroenoxysilanes has been developed. This protocol is characterized by its high efficiency and mild reaction conditions, offering a supplementary strategy for synthesis of α,α-difluoro-β-ketosthioethers.
ISSN:2052-4110
2052-4110
DOI:10.1039/d4qo00539b