Preparation and Properties of Carbonyl Iron/Fe+2Fe2+3O4 with Oxidation Blackening

High-temperature stealth technology continues to face severe challenges, and the development of oxidation-resistant stealth materials is critical. In this work, complex absorbers of carbonyl iron/Fe +2 Fe 2 +3 O 4 were prepared by an oxidation blackening method at room temperature, and the thermal s...

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Bibliographic Details
Published in:Journal of electronic materials 2024-07, Vol.53 (7), p.4030-4038
Main Authors: Gao, Hui, Chen, Yasu, Chen, Hongyu, Ma, Junjie, Li, Yang, Yuan, Kai, Zhou, Rui, Qu, Yongping
Format: Article
Language:English
Subjects:
Absorbers
Blackening
Carbonyls
Characterization and Evaluation of Materials
Chemical composition
Chemistry and Materials Science
Complex permittivity
Electronics and Microelectronics
High temperature
Instrumentation
Iron
Materials Science
Optical and Electronic Materials
Original Research Article
Oxidation
Oxidation resistance
Room temperature
Solid State Physics
Stealth technology
Superhigh frequencies
Thermal stability
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Summary:High-temperature stealth technology continues to face severe challenges, and the development of oxidation-resistant stealth materials is critical. In this work, complex absorbers of carbonyl iron/Fe +2 Fe 2 +3 O 4 were prepared by an oxidation blackening method at room temperature, and the thermal stability of the complex absorbers was investigated. The effect of oxidation time on the chemical composition and surface morphology of the carbonyl iron was assessed. The electromagnetic and absorption properties of the composites before and after oxidation were analyzed, and results showed that the diffraction peak of Fe +2 Fe 2 +3 O 4 increased after oxidation for 6 h at room temperature. Scanning electron microscopy coupled with energy-dispersive spectroscopy showed that the density of the Fe +2 Fe 2 +3 O 4 increased, and the surface of the carbonyl iron was completely coated with Fe +2 Fe 2 +3 O 4 after oxidation for 6 h. The complex permittivity increased and the complex permeability decreased by oxidizing blackening at room temperature. After oxidation for 6 h, the reflection loss of the composite was less than −5 dB in the whole X-band. The complex absorbers of carbonyl iron/Fe +2 Fe 2 +3 O 4 prepared by oxidation blackening at room temperature have great application prospects in the field of radar stealth materials.
ISSN:0361-5235
1543-186X
DOI:10.1007/s11664-024-11023-x