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Fuel Bioadditives Synthesis from Furfural Glycerol Condensation over Vanadium-Substituted Cesium Phosphomolybdate Salts
In this work, vanadium-substituted cesium phosphomolybdate salts were evaluated as catalysts in glycerol furfural condensation reactions, an attractive route to produce fuel-green bioadditives. Molybdenum atoms of phosphomolybdic acid were substituted with vanadium and precipitated as cesium salts g...
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| Published in: | Catalysis letters 2024-07, Vol.154 (7), p.3251-3263 |
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| creator | da Silva, Márcio José Ribeiro, Claúdio Andrade Júnior Rodrigues, Alana Alves Silva, Tiago Almeida |
| description | In this work, vanadium-substituted cesium phosphomolybdate salts were evaluated as catalysts in glycerol furfural condensation reactions, an attractive route to produce fuel-green bioadditives. Molybdenum atoms of phosphomolybdic acid were substituted with vanadium and precipitated as cesium salts generating catalysts with general formulae Cs
3+n
PMo
12-n
V
n
O
40
(n = 1–3). Among the salts evaluated, Cs
4
PMo
11
V
1
O
40
was the most active and selective catalyst toward the glyceryl furfural acetals, isomers (dioxolane: dioxane) were obtained at 2: 1 molar ratio with 90% conversion after a 2 h reaction at room temperature. The effect of main reaction parameters such as the glycerol: furfural molar ratio, the catalyst load, solvent, vanadium load, and the temperature were studied. The use of a solid, active, and easily synthesizable catalyst makes this an attractive route to produce fuel bioadditives from renewable raw materials at room temperature.
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| doi_str_mv | 10.1007/s10562-023-04558-x |
| format | article |
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3+n
PMo
12-n
V
n
O
40
(n = 1–3). Among the salts evaluated, Cs
4
PMo
11
V
1
O
40
was the most active and selective catalyst toward the glyceryl furfural acetals, isomers (dioxolane: dioxane) were obtained at 2: 1 molar ratio with 90% conversion after a 2 h reaction at room temperature. The effect of main reaction parameters such as the glycerol: furfural molar ratio, the catalyst load, solvent, vanadium load, and the temperature were studied. The use of a solid, active, and easily synthesizable catalyst makes this an attractive route to produce fuel bioadditives from renewable raw materials at room temperature.
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3+n
PMo
12-n
V
n
O
40
(n = 1–3). Among the salts evaluated, Cs
4
PMo
11
V
1
O
40
was the most active and selective catalyst toward the glyceryl furfural acetals, isomers (dioxolane: dioxane) were obtained at 2: 1 molar ratio with 90% conversion after a 2 h reaction at room temperature. The effect of main reaction parameters such as the glycerol: furfural molar ratio, the catalyst load, solvent, vanadium load, and the temperature were studied. The use of a solid, active, and easily synthesizable catalyst makes this an attractive route to produce fuel bioadditives from renewable raw materials at room temperature.
Graphical Abstract</description><subject>Acetals</subject><subject>Acids</subject><subject>Alternative energy sources</subject><subject>Biodiesel fuels</subject><subject>Biomass</subject><subject>Carbon</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Cellulose</subject><subject>Cesium</subject><subject>Chemical synthesis</subject><subject>Chemicals</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Energy consumption</subject><subject>Fuels</subject><subject>Furfural</subject><subject>Glycerol</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Organometallic Chemistry</subject><subject>Phosphomolybdic acid</subject><subject>Physical Chemistry</subject><subject>Polymers</subject><subject>Raw materials</subject><subject>Room temperature</subject><subject>Scanning electron microscopy</subject><subject>Solvents</subject><subject>Substitutes</subject><subject>Vanadium</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kE1Lw0AQhoMoWKt_wNOC59XZTdIkRw22CgWFqvS2bDazNiXJ1v2o7b83WsGbp5nD-7zDPFF0yeCaAWQ3jkE64RR4TCFJ05zujqIRSzNO86xYHg87MEbjjC9PozPn1gBQZKwYRZ_TgC25a4ys68Y3W3Rkse_9Cl3jiLamI9NgdbCyJbN2r9CalpSmr7F30jemJ2aLlrzJXtZN6OgiVM43PnisSTl0hI48r4zbrExn2n1VS49kIVvvzqMTLVuHF79zHL1O71_KBzp_mj2Wt3OqeAaeFlqBBuA6z3OGiYYJQpHXqdJcxYBM5QnEqcqKJGZpXaEansIiqRJZVXlVpfE4ujr0bqz5COi8WJtg--GkiGGSMT4pEjak-CGlrHHOohYb23TS7gUD8S1YHASLQbD4ESx2AxQfIDeE-3e0f9X_UF8UsIHX</recordid><startdate>20240701</startdate><enddate>20240701</enddate><creator>da Silva, Márcio José</creator><creator>Ribeiro, Claúdio Andrade Júnior</creator><creator>Rodrigues, Alana Alves</creator><creator>Silva, Tiago Almeida</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-0060-0551</orcidid></search><sort><creationdate>20240701</creationdate><title>Fuel Bioadditives Synthesis from Furfural Glycerol Condensation over Vanadium-Substituted Cesium Phosphomolybdate Salts</title><author>da Silva, Márcio José ; Ribeiro, Claúdio Andrade Júnior ; Rodrigues, Alana Alves ; Silva, Tiago Almeida</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-9fc0f002f8881e4f06e098d5cf2c30e1c84035c794315dbec719e94b4abb8bb53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Acetals</topic><topic>Acids</topic><topic>Alternative energy sources</topic><topic>Biodiesel fuels</topic><topic>Biomass</topic><topic>Carbon</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Cellulose</topic><topic>Cesium</topic><topic>Chemical synthesis</topic><topic>Chemicals</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Energy consumption</topic><topic>Fuels</topic><topic>Furfural</topic><topic>Glycerol</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Organometallic Chemistry</topic><topic>Phosphomolybdic acid</topic><topic>Physical Chemistry</topic><topic>Polymers</topic><topic>Raw materials</topic><topic>Room temperature</topic><topic>Scanning electron microscopy</topic><topic>Solvents</topic><topic>Substitutes</topic><topic>Vanadium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>da Silva, Márcio José</creatorcontrib><creatorcontrib>Ribeiro, Claúdio Andrade Júnior</creatorcontrib><creatorcontrib>Rodrigues, Alana Alves</creatorcontrib><creatorcontrib>Silva, Tiago Almeida</creatorcontrib><collection>CrossRef</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>da Silva, Márcio José</au><au>Ribeiro, Claúdio Andrade Júnior</au><au>Rodrigues, Alana Alves</au><au>Silva, Tiago Almeida</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fuel Bioadditives Synthesis from Furfural Glycerol Condensation over Vanadium-Substituted Cesium Phosphomolybdate Salts</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2024-07-01</date><risdate>2024</risdate><volume>154</volume><issue>7</issue><spage>3251</spage><epage>3263</epage><pages>3251-3263</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>In this work, vanadium-substituted cesium phosphomolybdate salts were evaluated as catalysts in glycerol furfural condensation reactions, an attractive route to produce fuel-green bioadditives. Molybdenum atoms of phosphomolybdic acid were substituted with vanadium and precipitated as cesium salts generating catalysts with general formulae Cs
3+n
PMo
12-n
V
n
O
40
(n = 1–3). Among the salts evaluated, Cs
4
PMo
11
V
1
O
40
was the most active and selective catalyst toward the glyceryl furfural acetals, isomers (dioxolane: dioxane) were obtained at 2: 1 molar ratio with 90% conversion after a 2 h reaction at room temperature. The effect of main reaction parameters such as the glycerol: furfural molar ratio, the catalyst load, solvent, vanadium load, and the temperature were studied. The use of a solid, active, and easily synthesizable catalyst makes this an attractive route to produce fuel bioadditives from renewable raw materials at room temperature.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-023-04558-x</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-0060-0551</orcidid></addata></record> |
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| subjects | Acetals Acids Alternative energy sources Biodiesel fuels Biomass Carbon Catalysis Catalysts Cellulose Cesium Chemical synthesis Chemicals Chemistry Chemistry and Materials Science Energy consumption Fuels Furfural Glycerol Industrial Chemistry/Chemical Engineering Organometallic Chemistry Phosphomolybdic acid Physical Chemistry Polymers Raw materials Room temperature Scanning electron microscopy Solvents Substitutes Vanadium |
| title | Fuel Bioadditives Synthesis from Furfural Glycerol Condensation over Vanadium-Substituted Cesium Phosphomolybdate Salts |
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