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5Ni/MgO and 5Ni/MgO + MOx (M = Zr, Ti, Al) Catalyst for Hydrogen Production via Dry Reforming of Methane: Promotor-Free, Cost-Effective, and Handy Catalyst System
Utilization of CO 2 as a promising oxidant under dry reforming methane (DRM) can mitigate two greenhouse gases (CO 2 and CH 4 ) together, as well as DRM reaction may be a source of H 2 energy in future. The cost-effective and handy catalyst preparation procedures like mixing, drying and calcining ma...
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| Published in: | Catalysis letters 2024-07, Vol.154 (7), p.3441-3456 |
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| Main Authors: | , , , , , , , |
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| container_issue | 7 |
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| container_title | Catalysis letters |
| container_volume | 154 |
| creator | Patel, Naitik Al-Fatesh, Ahmed S. Bamatraf, Nouf A. Osman, Ahmed I. Alreshaidan, Salwa B. Fakeeha, Anis H. Wazeer, Irfan Kumar, Rawesh |
| description | Utilization of CO
2
as a promising oxidant under dry reforming methane (DRM) can mitigate two greenhouse gases (CO
2
and CH
4
) together, as well as DRM reaction may be a source of H
2
energy in future. The cost-effective and handy catalyst preparation procedures like mixing, drying and calcining may turn this reaction from lab to industry. In this line, herein, 5Ni/MgO and 5Ni/MgO + MO
x
(M = Zr, Ti, Al) catalysts were prepared, investigated for DRM and characterized by X-ray diffraction, Raman, temperature programmed reduction/desorption, thermogravimetry and transmission electron microscope. Among the prepared catalysts, the 5Ni/MgO + TiO
2
catalyst exhibits the highest concentration of active Ni sites enhanced reducibility under oxidizing and reducing environments, but catalytic excellency is hindered by severe graphitic-type coke deposition. On the other hand, the 5Ni/MgO + Al
2
O
3
catalyst predominantly comprises metallic Ni resulting from the reduction of “strongly interacted NiO”, expanded surface area and the highest concentration of easily accessible active sites, contributing to its superior performance (H
2
yield ~ 71% up to 430 min time on stream) under oxidizing and reducing conditions during DRM. The outstanding performance of the 5Ni/MgO + Al
2
O
3
catalyst marks a significant stride towards the development of an industrially viable, cost-effective, and convenient catalyst system for DRM.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-023-04548-z |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3067126975</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3067126975</sourcerecordid><originalsourceid>FETCH-LOGICAL-c314t-ac12ee4f7ebf27f3ebfbdaf4d0ec289028a579526cc75b4346b636f1dd52fb673</originalsourceid><addsrcrecordid>eNp9kc1KAzEUhQdRUKsv4CrgRrGx-ZlMOoKLUlsrtFa0grgJmZmkjrSTmkyL05VbX8XH8klMrdCdi3vvCXzn3sAJgiOMzjFCvOEwYhGBiFCIQhY24XIr2MOME9jk8dO21whjSDl52g32nXtFCMUcx3vBF7vNG4PxEMgiA3_6--PzzNdg-A5OBl5c-nq2dTDK66A1OQVtWcpJ5UqgjQW9KrNmrApwZ002T8vcFGCRS3BlK3CvPDHNizEwGgxU-SILdbECp6Y0FnatUnXQNq6EHa2V9y78e_WRnm_V5s6Db2p6EOxoOXHq8G_WgsduZ9Tuwf7w-qbd6sOU4rCEMsVEqVBzlWjCNfUjyaQOM6RS0owRaUrGY0aiNOUsCWkYJRGNNM4yRnQScVoLjtd7Z9a8zZUrxauZ28KfFBRFHJMo5sxTZE2l1jhnlRYzm0-lrQRGYpWJWGcifCbiNxOx9Ca6NjkPF2NlN6v_cf0ArvmTLA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3067126975</pqid></control><display><type>article</type><title>5Ni/MgO and 5Ni/MgO + MOx (M = Zr, Ti, Al) Catalyst for Hydrogen Production via Dry Reforming of Methane: Promotor-Free, Cost-Effective, and Handy Catalyst System</title><source>Springer Nature</source><creator>Patel, Naitik ; Al-Fatesh, Ahmed S. ; Bamatraf, Nouf A. ; Osman, Ahmed I. ; Alreshaidan, Salwa B. ; Fakeeha, Anis H. ; Wazeer, Irfan ; Kumar, Rawesh</creator><creatorcontrib>Patel, Naitik ; Al-Fatesh, Ahmed S. ; Bamatraf, Nouf A. ; Osman, Ahmed I. ; Alreshaidan, Salwa B. ; Fakeeha, Anis H. ; Wazeer, Irfan ; Kumar, Rawesh</creatorcontrib><description>Utilization of CO
2
as a promising oxidant under dry reforming methane (DRM) can mitigate two greenhouse gases (CO
2
and CH
4
) together, as well as DRM reaction may be a source of H
2
energy in future. The cost-effective and handy catalyst preparation procedures like mixing, drying and calcining may turn this reaction from lab to industry. In this line, herein, 5Ni/MgO and 5Ni/MgO + MO
x
(M = Zr, Ti, Al) catalysts were prepared, investigated for DRM and characterized by X-ray diffraction, Raman, temperature programmed reduction/desorption, thermogravimetry and transmission electron microscope. Among the prepared catalysts, the 5Ni/MgO + TiO
2
catalyst exhibits the highest concentration of active Ni sites enhanced reducibility under oxidizing and reducing environments, but catalytic excellency is hindered by severe graphitic-type coke deposition. On the other hand, the 5Ni/MgO + Al
2
O
3
catalyst predominantly comprises metallic Ni resulting from the reduction of “strongly interacted NiO”, expanded surface area and the highest concentration of easily accessible active sites, contributing to its superior performance (H
2
yield ~ 71% up to 430 min time on stream) under oxidizing and reducing conditions during DRM. The outstanding performance of the 5Ni/MgO + Al
2
O
3
catalyst marks a significant stride towards the development of an industrially viable, cost-effective, and convenient catalyst system for DRM.
Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-023-04548-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Alumina ; Aluminum oxide ; Carbon dioxide ; Catalysis ; Catalysts ; Chemical engineering ; Chemistry ; Chemistry and Materials Science ; Drying ; Greenhouse gases ; Hydrogen ; Hydrogen production ; Industrial Chemistry/Chemical Engineering ; Magnesium oxide ; Metal oxides ; Methane ; Nitrates ; Organometallic Chemistry ; Oxidation ; Oxidizing agents ; Phase transitions ; Physical Chemistry ; Reforming ; Solid solutions ; Temperature ; Thermogravimetry ; Titanium ; Titanium dioxide ; Transmission electron microscopy ; Zirconium</subject><ispartof>Catalysis letters, 2024-07, Vol.154 (7), p.3441-3456</ispartof><rights>The Author(s) 2024</rights><rights>The Author(s) 2024. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c314t-ac12ee4f7ebf27f3ebfbdaf4d0ec289028a579526cc75b4346b636f1dd52fb673</cites><orcidid>0000-0003-2788-7839</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Patel, Naitik</creatorcontrib><creatorcontrib>Al-Fatesh, Ahmed S.</creatorcontrib><creatorcontrib>Bamatraf, Nouf A.</creatorcontrib><creatorcontrib>Osman, Ahmed I.</creatorcontrib><creatorcontrib>Alreshaidan, Salwa B.</creatorcontrib><creatorcontrib>Fakeeha, Anis H.</creatorcontrib><creatorcontrib>Wazeer, Irfan</creatorcontrib><creatorcontrib>Kumar, Rawesh</creatorcontrib><title>5Ni/MgO and 5Ni/MgO + MOx (M = Zr, Ti, Al) Catalyst for Hydrogen Production via Dry Reforming of Methane: Promotor-Free, Cost-Effective, and Handy Catalyst System</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Utilization of CO
2
as a promising oxidant under dry reforming methane (DRM) can mitigate two greenhouse gases (CO
2
and CH
4
) together, as well as DRM reaction may be a source of H
2
energy in future. The cost-effective and handy catalyst preparation procedures like mixing, drying and calcining may turn this reaction from lab to industry. In this line, herein, 5Ni/MgO and 5Ni/MgO + MO
x
(M = Zr, Ti, Al) catalysts were prepared, investigated for DRM and characterized by X-ray diffraction, Raman, temperature programmed reduction/desorption, thermogravimetry and transmission electron microscope. Among the prepared catalysts, the 5Ni/MgO + TiO
2
catalyst exhibits the highest concentration of active Ni sites enhanced reducibility under oxidizing and reducing environments, but catalytic excellency is hindered by severe graphitic-type coke deposition. On the other hand, the 5Ni/MgO + Al
2
O
3
catalyst predominantly comprises metallic Ni resulting from the reduction of “strongly interacted NiO”, expanded surface area and the highest concentration of easily accessible active sites, contributing to its superior performance (H
2
yield ~ 71% up to 430 min time on stream) under oxidizing and reducing conditions during DRM. The outstanding performance of the 5Ni/MgO + Al
2
O
3
catalyst marks a significant stride towards the development of an industrially viable, cost-effective, and convenient catalyst system for DRM.
Graphical Abstract</description><subject>Alumina</subject><subject>Aluminum oxide</subject><subject>Carbon dioxide</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical engineering</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Drying</subject><subject>Greenhouse gases</subject><subject>Hydrogen</subject><subject>Hydrogen production</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Magnesium oxide</subject><subject>Metal oxides</subject><subject>Methane</subject><subject>Nitrates</subject><subject>Organometallic Chemistry</subject><subject>Oxidation</subject><subject>Oxidizing agents</subject><subject>Phase transitions</subject><subject>Physical Chemistry</subject><subject>Reforming</subject><subject>Solid solutions</subject><subject>Temperature</subject><subject>Thermogravimetry</subject><subject>Titanium</subject><subject>Titanium dioxide</subject><subject>Transmission electron microscopy</subject><subject>Zirconium</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kc1KAzEUhQdRUKsv4CrgRrGx-ZlMOoKLUlsrtFa0grgJmZmkjrSTmkyL05VbX8XH8klMrdCdi3vvCXzn3sAJgiOMzjFCvOEwYhGBiFCIQhY24XIr2MOME9jk8dO21whjSDl52g32nXtFCMUcx3vBF7vNG4PxEMgiA3_6--PzzNdg-A5OBl5c-nq2dTDK66A1OQVtWcpJ5UqgjQW9KrNmrApwZ002T8vcFGCRS3BlK3CvPDHNizEwGgxU-SILdbECp6Y0FnatUnXQNq6EHa2V9y78e_WRnm_V5s6Db2p6EOxoOXHq8G_WgsduZ9Tuwf7w-qbd6sOU4rCEMsVEqVBzlWjCNfUjyaQOM6RS0owRaUrGY0aiNOUsCWkYJRGNNM4yRnQScVoLjtd7Z9a8zZUrxauZ28KfFBRFHJMo5sxTZE2l1jhnlRYzm0-lrQRGYpWJWGcifCbiNxOx9Ca6NjkPF2NlN6v_cf0ArvmTLA</recordid><startdate>20240701</startdate><enddate>20240701</enddate><creator>Patel, Naitik</creator><creator>Al-Fatesh, Ahmed S.</creator><creator>Bamatraf, Nouf A.</creator><creator>Osman, Ahmed I.</creator><creator>Alreshaidan, Salwa B.</creator><creator>Fakeeha, Anis H.</creator><creator>Wazeer, Irfan</creator><creator>Kumar, Rawesh</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2788-7839</orcidid></search><sort><creationdate>20240701</creationdate><title>5Ni/MgO and 5Ni/MgO + MOx (M = Zr, Ti, Al) Catalyst for Hydrogen Production via Dry Reforming of Methane: Promotor-Free, Cost-Effective, and Handy Catalyst System</title><author>Patel, Naitik ; Al-Fatesh, Ahmed S. ; Bamatraf, Nouf A. ; Osman, Ahmed I. ; Alreshaidan, Salwa B. ; Fakeeha, Anis H. ; Wazeer, Irfan ; Kumar, Rawesh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c314t-ac12ee4f7ebf27f3ebfbdaf4d0ec289028a579526cc75b4346b636f1dd52fb673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Alumina</topic><topic>Aluminum oxide</topic><topic>Carbon dioxide</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical engineering</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Drying</topic><topic>Greenhouse gases</topic><topic>Hydrogen</topic><topic>Hydrogen production</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Magnesium oxide</topic><topic>Metal oxides</topic><topic>Methane</topic><topic>Nitrates</topic><topic>Organometallic Chemistry</topic><topic>Oxidation</topic><topic>Oxidizing agents</topic><topic>Phase transitions</topic><topic>Physical Chemistry</topic><topic>Reforming</topic><topic>Solid solutions</topic><topic>Temperature</topic><topic>Thermogravimetry</topic><topic>Titanium</topic><topic>Titanium dioxide</topic><topic>Transmission electron microscopy</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Patel, Naitik</creatorcontrib><creatorcontrib>Al-Fatesh, Ahmed S.</creatorcontrib><creatorcontrib>Bamatraf, Nouf A.</creatorcontrib><creatorcontrib>Osman, Ahmed I.</creatorcontrib><creatorcontrib>Alreshaidan, Salwa B.</creatorcontrib><creatorcontrib>Fakeeha, Anis H.</creatorcontrib><creatorcontrib>Wazeer, Irfan</creatorcontrib><creatorcontrib>Kumar, Rawesh</creatorcontrib><collection>SpringerOpen(OpenAccess)</collection><collection>CrossRef</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Patel, Naitik</au><au>Al-Fatesh, Ahmed S.</au><au>Bamatraf, Nouf A.</au><au>Osman, Ahmed I.</au><au>Alreshaidan, Salwa B.</au><au>Fakeeha, Anis H.</au><au>Wazeer, Irfan</au><au>Kumar, Rawesh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>5Ni/MgO and 5Ni/MgO + MOx (M = Zr, Ti, Al) Catalyst for Hydrogen Production via Dry Reforming of Methane: Promotor-Free, Cost-Effective, and Handy Catalyst System</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2024-07-01</date><risdate>2024</risdate><volume>154</volume><issue>7</issue><spage>3441</spage><epage>3456</epage><pages>3441-3456</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Utilization of CO
2
as a promising oxidant under dry reforming methane (DRM) can mitigate two greenhouse gases (CO
2
and CH
4
) together, as well as DRM reaction may be a source of H
2
energy in future. The cost-effective and handy catalyst preparation procedures like mixing, drying and calcining may turn this reaction from lab to industry. In this line, herein, 5Ni/MgO and 5Ni/MgO + MO
x
(M = Zr, Ti, Al) catalysts were prepared, investigated for DRM and characterized by X-ray diffraction, Raman, temperature programmed reduction/desorption, thermogravimetry and transmission electron microscope. Among the prepared catalysts, the 5Ni/MgO + TiO
2
catalyst exhibits the highest concentration of active Ni sites enhanced reducibility under oxidizing and reducing environments, but catalytic excellency is hindered by severe graphitic-type coke deposition. On the other hand, the 5Ni/MgO + Al
2
O
3
catalyst predominantly comprises metallic Ni resulting from the reduction of “strongly interacted NiO”, expanded surface area and the highest concentration of easily accessible active sites, contributing to its superior performance (H
2
yield ~ 71% up to 430 min time on stream) under oxidizing and reducing conditions during DRM. The outstanding performance of the 5Ni/MgO + Al
2
O
3
catalyst marks a significant stride towards the development of an industrially viable, cost-effective, and convenient catalyst system for DRM.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-023-04548-z</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0003-2788-7839</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 2024-07, Vol.154 (7), p.3441-3456 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_journals_3067126975 |
| source | Springer Nature |
| subjects | Alumina Aluminum oxide Carbon dioxide Catalysis Catalysts Chemical engineering Chemistry Chemistry and Materials Science Drying Greenhouse gases Hydrogen Hydrogen production Industrial Chemistry/Chemical Engineering Magnesium oxide Metal oxides Methane Nitrates Organometallic Chemistry Oxidation Oxidizing agents Phase transitions Physical Chemistry Reforming Solid solutions Temperature Thermogravimetry Titanium Titanium dioxide Transmission electron microscopy Zirconium |
| title | 5Ni/MgO and 5Ni/MgO + MOx (M = Zr, Ti, Al) Catalyst for Hydrogen Production via Dry Reforming of Methane: Promotor-Free, Cost-Effective, and Handy Catalyst System |
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