Comparative thermodynamic analysis of gold dissolution in four organic carboxylic acid-catalyzed thiosulfate systems using Eh–pH and species distribution diagrams

• Published in: Journal of Central South University 2024-05, Vol.31 (5), p.1461-1475
• Main Authors: Chen, Jun-nan, Xie, Feng, Wang, Wei, Bai, Yun-long
• Format: Article
• Language: English
• Subjects: Acids; Ammonia; Ammonia pressure leaching; Carboxylic acids; Citric acid; Copper; Engineering; Gold; Leaching; Malic acid; Metallic Materials; Oxalic acid; Tartaric acid; Thermodynamics; Thiosulfates
• ISSN: 2095-2899; 2227-5223
• DOI: 10.1007/s11771-024-5572-0

The non-ammonia thiosulfate leaching system is considered to be an attractive and eco-friendly route for gold leaching without the usage of cyanide or ammonia. In this paper, the role of four organic carboxylic acids, named oxalic acid (Ox), malic acid (Mal), citric acid (Cit), and tartaric acid (Tart) in copper-thiosulfate system has been studied comparatively. Based on the available thermodynamic data, a series of E h –pH and species distribution diagrams for copper-Ox/Mal/Cit/Tart-thiosulfate system under various conditions have been constructed from thermodynamic calculation. The results show that thiosulfate is the only effective complexing agent for aurous ions, while the organic carboxylic acids work as a copper ligand. The copper-Mal/Cit/Tart-thiosulfate system exhibits potential advantages over the traditional copper-ammonia-thiosulfate system, such as wider pH range and lower thiosulfate consumption. The calculation also indicates the redox potentials of Cu(II)/Cu(I) for the leaching systems are in the subsequence of E 0 [Cu(Ox) 2 2− /Cu(S 2 O 3 ) 3 5− ] > E 0 [Cu(NH 3 ) 4 2+ /Cu(S 2 O 3 ) 3 5− ] > E 0 [Cu 2 (Mal) 2 H −2 2− /Cu(S 2 O 3 ) 3 5− ] ≈ E 0 [Cu 2 (Cit) 2 H −2 4− /Cu(S 2 O 3 ) 3 5− ] > E 0 [Cu(Tart) 2 H −4 6− /Cu(S 2 O 3 ) 3 5− ]. Increasing thiosulfate concentration leads to a sharp decline in the content of copper-Ox/Mal/Cit/Tart complex, and the stability of the formed cupric complex follows the descending order of tartaric acid>citric acid>malic acid>oxalic acid.