Synthesis and Characterization of a New Non-Linear Optical Material: (4-Chlorophenyl)(4-Hydroxypiperidin-1-yl) Methanone

A new organic and nonlinear optical material namely (4-chlorophenyl) (4-hydroxypiperidin-1-yl) methanone [HPCP] was synthesized from the mixture of 4-hydroxypiperidiene, triethylamine, and 4-chlorobenzoyl chloride by solution growth technique. The 3D structure of the title crystal has been derived u...

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Published in:Polycyclic aromatic compounds 2024-05, Vol.44 (5), p.3222-3232
Main Authors: Revathi, B K, Reuben, Jonathan D, Sathya, S, Krishna, Priya M, Anish, Fathima A, Yuvashri, R, Usha, G
Format: Article
Language:English
Subjects:
Crystallization
Diamond pyramid hardness
Differential thermal analysis
FTIR
HNMR
Mechanical properties
Melting point
Melting points
Neodymium lasers
NMR
Nonlinear optics
Nuclear magnetic resonance
Optical materials
Optical properties
Q switched lasers
Second harmonic generation
SHG efficiency
single-crystal XRD
Synthesis
TG/DTA
Thermal analysis
Thermal stability
Triethylamine
vickers microhardness
X-ray diffraction
YAG lasers
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container_end_page 3232
container_issue 5
container_start_page 3222
container_title Polycyclic aromatic compounds
container_volume 44
creator Revathi, B K
Reuben, Jonathan D
Sathya, S
Krishna, Priya M
Anish, Fathima A
Yuvashri, R
Usha, G
description A new organic and nonlinear optical material namely (4-chlorophenyl) (4-hydroxypiperidin-1-yl) methanone [HPCP] was synthesized from the mixture of 4-hydroxypiperidiene, triethylamine, and 4-chlorobenzoyl chloride by solution growth technique. The 3D structure of the title crystal has been derived using the X-ray diffraction (XRD) spectrum. The compound was crystallized in the orthorhombic crystal system with non-centrosymmetric space group Pca2 1 . Optical properties of the as-grown compound have been elucidated through 1 H-NMR, UV-Visible, FTIR, and PL spectral studies. The melting point, stages of mass decay, and thermal stability of the synthesized material were obtained by TG/DTA thermal analysis. Vickers microhardness test was performed to comprehend its mechanical strength. The second harmonic generation (SHG) efficiency was estimated by employing Q-switched high energy, Nd: YAG the laser source, and the SHG efficiency was found to be 1.73 times that of KDP, the reference crystal.
doi_str_mv 10.1080/10406638.2023.2232510
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source Taylor and Francis Science and Technology Collection
subjects Crystallization
Diamond pyramid hardness
Differential thermal analysis
FTIR
HNMR
Mechanical properties
Melting point
Melting points
Neodymium lasers
NMR
Nonlinear optics
Nuclear magnetic resonance
Optical materials
Optical properties
Q switched lasers
Second harmonic generation
SHG efficiency
single-crystal XRD
Synthesis
TG/DTA
Thermal analysis
Thermal stability
Triethylamine
vickers microhardness
X-ray diffraction
YAG lasers
title Synthesis and Characterization of a New Non-Linear Optical Material: (4-Chlorophenyl)(4-Hydroxypiperidin-1-yl) Methanone
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