Yellow rare earth sulfide powders with near‐infrared reflectance and spectral modulation for energy‐saving applications

• Published in: Journal of the American Ceramic Society 2024-09, Vol.107 (9), p.6060-6069
• Main Authors: Xu, Wenhao, Bai, Gongxun, Zhang, Hongbin, Li, Denghao, Xu, Shiqing
• Format: Article
• Language: English
• Subjects: Alkali metals; Chemical synthesis; colorants and pigments; Cooling; Doping; Energy bands; Functional materials; Infrared reflection; Near infrared radiation; optical properties; Pigments; Polyvinylidene fluorides; radiative cooling; rare earth; Reflectance
• ISSN: 0002-7820; 1551-2916
• DOI: 10.1111/jace.19854

Radiative cooling pigments offer new opportunities for sustainable carbon neutrality as zero‐energy and zero‐pollution functional materials. However, it is a challenge to prepare inorganic yellow pigments simultaneously with environmentally friendly, high color value, and weather resistance. In this study, a series of alkali metal‐doped γ‐Sm2S3 yellow pigments with near‐infrared reflectance were synthesized. The doping of alkali metal ions reduced synthesis temperature of Sm2S3 from 1300°C to 1000°C. The change in energy band structure induced by alkali metal doping allows the products to exhibit modifiable colors. Typical γ‐[Na]‐Sm2S3 pigment powders have a high near‐infrared reflectance and impressive colors (b* = 78.6, C* = 77.6). Furthermore, colored films made by prepared yellow powders with polyvinylidene fluoride in certain ratios had high near‐infrared reflectance and excellent environmental weathering, resulting in an effective cooling of 4–8°C in outdoor experiments. This work expands the range of options for energy‐efficient building and yellow colorant. Building energy efficiency application diagram and outdoor experimental performance of yellow γ‐Sm2S3 pigments for daytime passive cooling.