Development of Durable Zn–MnO2 Battery via a Functionalized Hydrogel Film

• Published in: Advanced energy materials 2024-07, Vol.14 (25), p.n/a
• Main Authors: Zheng, Xinhua, Xu, Kui, Ma, Yirui, Sun, Jifei, Han, Bibo, Luo, Ruihao, Wang, Mingming, Chen, Na, Song, Li, Zhao, Qingbiao, Chen, Wei
• Format: Article
• Language: English
• Subjects: Crosslinking; Cycles; Electric vehicles; Energy storage; high areal capacity; hydrogel film; Hydrogels; large‐scale energy storage; long cycle life; Manganese dioxide; Polyacrylamide; Solvation; Zn–MnO2 battery
• ISSN: 1614-6832; 1614-6840
• DOI: 10.1002/aenm.202400038

Aqueous zinc (Zn) battery with remarkable advantages of high safety, low cost, and high reversibility is highly applauded in next‐generation low‐speed electric vehicles and large‐scale energy storage applications. However, Zn anode suffers from a series of unfavorable reactions, hindering its progress toward industrialization. Herein, a functionalized hydrogel film is designed using polydopamine and polyacrylamide crosslinking (PDAM) as the Zn protective layer to stabilize the Zn anode. Benefiting from the strong interaction of Zn2+ with PDAM, the primary solvation shell of Zn2+ is regulated by PDAM into the form of PDAM–Zn2+‐5H2O. This remodeling prevents Zn dendrite growth and inhibits water‐induced side reactions. As a result, the Zn–MnO2 battery using PDAM‐coated Zn anode exhibits excellent cycling stability, demonstrating over 1150 cycles at an areal capacity of 5 mAh cm−2 with an average Coulombic efficiency (CE) of 96.5%. For a scaled‐up PDAM@Zn–MnO2 pouch cell with a capacity of 80 mAh, stable cycling of over 200 cycles with an average CE of 91.9% is achieved. The superior Zn–MnO2 battery enabled by the functionalized hydrogel protective film enlightens an arena toward next‐generation energy storage applications. This paper designs a functionalized hydrogel film using polydopamine and polyacrylamide crosslinking (PDAM) as the Zn protective layer to stabilize the Zn anode. The constructed Zn–MnO2 battery using PDAM‐coated Zn anode exhibits 1150 stable cycles at 5 mAh cm−2, while still demonstrates excellent cycling stability when the areal capacity is extended to 10 mAh cm−2.