Effects of hexamethylenetetramine as an electrolyte additive on elevated temperature performance of graphite/LiMn2O4 batteries

Spinel LiMn 2 O 4 -based lithium-ion batteries are widely applied in electric two-wheeler and low-speed vehicles due to their low cost and low toxicity. Nevertheless, the Mn deposition at the anode originated from Mn dissolution of LiMn 2 O 4 causes a poor elevated temperature cycle life of graphite...

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Bibliographic Details
Published in:Ionics 2024, Vol.30 (7), p.3881-3893
Main Authors: Zheng, Tingting, Wang, Zhixing, Wang, Siwu, Li, Xinhai, Guo, Huajun, Peng, Wenjie, Wang, Jiexi, Yan, Guochun
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Density functional theory
Deposition
Effectiveness
Electrochemical analysis
Electrochemistry
Electrolytes
Energy Storage
Graphite
Hexamethylenetetramine
High temperature
Lithium manganese oxides
Lithium-ion batteries
Low speed
Optical and Electronic Materials
Raman spectroscopy
Rechargeable batteries
Renewable and Green Energy
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Summary:Spinel LiMn 2 O 4 -based lithium-ion batteries are widely applied in electric two-wheeler and low-speed vehicles due to their low cost and low toxicity. Nevertheless, the Mn deposition at the anode originated from Mn dissolution of LiMn 2 O 4 causes a poor elevated temperature cycle life of graphite/LiMn 2 O 4 batteries. Herein, a graphite/LiFePO 4 cell with specific Mn 2+ added in the electrolyte is provided as an efficient evaluation method to research Mn 2+ deposition. Besides, an effective strategy by adding a ligand hexamethylenetetramine (HMTA) as an electrolyte additive is proposed to prevent Mn 2+ depositing. HMTA effectively “locks in” Mn 2+ through strong coordination, as confirmed by Raman spectroscopy and density functional theory (DFT) calculations. Moreover, the CV and XPS results indicate that the adsorption of HMTA is able to significantly inhibit side reactions at the anode/electrolyte interface. By adopting this strategy, the capacity retention of graphite/LiMn 2 O 4 cell is enhanced from 68.9% to 79.0% at 0.5 C after 100 cycles under 60 °C when adding 0.5% HMTA additive into the blank electrolyte. This work provides a new insight into revealing the mechanism of Mn 2+ regulation by introducing HMTA and improving the electrochemical performance of graphite/LiMn 2 O 4 batteries at elevated temperature.
ISSN:0947-7047
1862-0760
DOI:10.1007/s11581-024-05558-6