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A reaction of 2-carbonyl-substituted 1H-benzo[f]chromenes with N-arylamides of cyanoacetic acid
A reaction of 2-trifluoroacetyl-1 H -benzo[ f ]chromenes with N -arylamides of cyanoacetic acid led to the synthesis of a series of 2-oxo-6-trifluoromethylpyridine-3-carboxamides as products of a cascade of the carbo-Michael reaction, Thorpe–Ziegler cyclization, and Dimroth rearrangement. In the cas...
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| Published in: | Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2024-04, Vol.60 (3-4), p.156-160 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c200t-365dadc46360028eb7cef00bfd83fb937d40b6e882269cd199e15c3662b3d7f83 |
| container_end_page | 160 |
| container_issue | 3-4 |
| container_start_page | 156 |
| container_title | Chemistry of heterocyclic compounds (New York, N.Y. 1965) |
| container_volume | 60 |
| creator | Osipov, Dmitry V. Krasnikov, Pavel E. Artemenko, Alina A. |
| description | A reaction of 2-trifluoroacetyl-1
H
-benzo[
f
]chromenes with
N
-arylamides of cyanoacetic acid led to the synthesis of a series of 2-oxo-6-trifluoromethylpyridine-3-carboxamides as products of a cascade of the carbo-Michael reaction, Thorpe–Ziegler cyclization, and Dimroth rearrangement. In the case of 1
H
-benzo[
f
]chromene-2-carbaldehydes, the corresponding Knoevenagel adducts were isolated. |
| doi_str_mv | 10.1007/s10593-024-03312-4 |
| format | article |
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H
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N
-arylamides of cyanoacetic acid led to the synthesis of a series of 2-oxo-6-trifluoromethylpyridine-3-carboxamides as products of a cascade of the carbo-Michael reaction, Thorpe–Ziegler cyclization, and Dimroth rearrangement. In the case of 1
H
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f
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H
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f
]chromenes with
N
-arylamides of cyanoacetic acid led to the synthesis of a series of 2-oxo-6-trifluoromethylpyridine-3-carboxamides as products of a cascade of the carbo-Michael reaction, Thorpe–Ziegler cyclization, and Dimroth rearrangement. In the case of 1
H
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f
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H
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f
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N
-arylamides of cyanoacetic acid led to the synthesis of a series of 2-oxo-6-trifluoromethylpyridine-3-carboxamides as products of a cascade of the carbo-Michael reaction, Thorpe–Ziegler cyclization, and Dimroth rearrangement. In the case of 1
H
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f
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| fulltext | fulltext |
| identifier | ISSN: 0009-3122 |
| ispartof | Chemistry of heterocyclic compounds (New York, N.Y. 1965), 2024-04, Vol.60 (3-4), p.156-160 |
| issn | 0009-3122 1573-8353 |
| language | eng |
| recordid | cdi_proquest_journals_3077944810 |
| source | Springer Link |
| subjects | Adducts Carbonyls Chemistry Chemistry and Materials Science Michael reaction Organic Chemistry Pharmacy |
| title | A reaction of 2-carbonyl-substituted 1H-benzo[f]chromenes with N-arylamides of cyanoacetic acid |
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