Deposition of Wear-Resistant Nanocomposite Coatings from Accelerated C60 Ions

• Published in: Surface investigation, x-ray, synchrotron and neutron techniques x-ray, synchrotron and neutron techniques, 2024-06, Vol.18 (3), p.557-563
• Main Authors: Pukha, V. E., Drozdova, E. I., Chernogorova, O. P., Lukina, I. N., Petrzhik, M. I., Belmesov, A. A.
• Format: Article
• Language: English
• Subjects: Beam leads; Buckminsterfullerene; Chemistry and Materials Science; Coatings; Coefficient of friction; Composite structures; Graphite; Hardness; Materials Science; Mechanical properties; Nanocomposites; Nanocrystals; Raman spectroscopy; Substrates; Surfaces and Interfaces; Thin Films; Tribology; Wear resistance
• ISSN: 1027-4510; 1819-7094
• DOI: 10.1134/S1027451024700101

From accelerated C 60 ions at temperatures of 200 and 300°C hard wear-resistant carbon coatings were deposited. It has been established that the mechanical properties of the coatings are determined by the substrate temperature ( T s ) and the energy composition of the beam. The hardness of coatings deposited from ions with an energy of 7 keV exceeds 50 GPa and is practically independent of T s . The presence of and with an energy of ~14 and 21 keV, respectively, in the beam leads to a result that is not typical for carbon coatings—the hardness increases by more than 1.3 times with an increase in T s from 200 to 300°C (from 31.6 to 41.6 GPa). In this case, according to Raman spectroscopy data, the size of graphite nanocrystals in the coating increases with temperature up to almost 2 nm. Coatings obtained under conditions of irradiation with and ions are characterized by minimal wear (1.5 × 10 –8 mm 3 /(N m), T s = 200°C) and minimal friction coefficient (μ = 0.05 for T s = 300°C). We attribute the unusual dependence of hardness on T s and the improvement in the tribological properties of coatings to the formation of a composite structure based on a diamond-like matrix and graphite nanocrystals in this T s range.