Relationship between the bandgap energy and photoluminescence properties of Pr3+-activated complex perovskite oxides by cation–nitrogen substitution

• Published in: New journal of chemistry 2024-07, Vol.48 (29), p.12912-12918
• Main Authors: Noda, Suzuka, Sato, Yasushi, Hasegawa, Takuya, Kakihana, Masato, Yin, Shu
• Format: Article
• Language: English
• Subjects: Electronic structure; Emission spectra; Energy gap; Energy levels; Excitation spectra; Light levels; Perovskites; Phosphors; Photoluminescence; Solid solutions; Ultraviolet radiation
• ISSN: 1144-0546; 1369-9261
• DOI: 10.1039/d3nj05682a

The photoluminescence properties of f–f emission-type phosphors strongly depend on the electronic structure of the host materials. This study investigated in detail the relationship between the bandgap energy and the photoluminescence properties of Pr3+-activated CaTa2/3Mg1/3O3–CaTaO2N solid solutions. Ca3Ta3−xMgxO6+3xN3−3x (0.00 ≦ x ≦ 1.00) were chosen as the host materials for the approach used herein. The bandgap energy level (Eg) for the Ca3Ta3−xMgxO6+3xN3−3x solid solutions was systematically changed from 2.7 to 5.1 eV by controlling the Mg/Ta and O/N ratios. The photoluminescence excitation and emission control was systematically performed by engineering Eg for the samples. In the excitation spectra, the maximum photoluminescence excitation wavelength shifted to a shorter wavelength according to the Eg expansion. In the emission spectra, the red emission assigned to the 1D2–3H4 levels of Pr3+ in the samples with x = 0.25–0.50 could be excited in near-UV light regions (350 nm) when the Eg in the host materials was adjusted to approximately 3.0 eV. Conversely, several emissions, including a green emission belonging to the 3P0–3H4 levels of Pr3+, were observed when the Eg of the samples with x = 0.75–0.95 became larger than 3.0 eV. The results indicate that the photoluminescence properties of the f–f emission-type phosphors are attributed to the Eg in the host materials.