Spectral Properties of Polymer Composites Doped with Boron Difluoride β-Ketoiminates

Luminescent polymer composites based on polycarbonate and polystyrene doped with boron difluoride β-ketoiminates have been synthesized. The luminescence properties of 12 dyes with various substituents have been studied. The effect of the boron difluoride β-ketoiminate concentration on the spectral p...

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Published in:High energy chemistry 2024-08, Vol.58 (4), p.375-381
Main Authors: Bodyk, R. E., Khrebtov, A. A., Tret’yakova, G. O., Fedorenko, E. V., Mirochnik, A. G.
Format: Article
Language:English
Subjects:
Boron
Chemistry
Chemistry and Materials Science
Difluorides
Dyes
Luminescence
Molecular Photonics
Optical properties
Physical Chemistry
Polymer matrix composites
Polymers
Polystyrene resins
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container_end_page 381
container_issue 4
container_start_page 375
container_title High energy chemistry
container_volume 58
creator Bodyk, R. E.
Khrebtov, A. A.
Tret’yakova, G. O.
Fedorenko, E. V.
Mirochnik, A. G.
description Luminescent polymer composites based on polycarbonate and polystyrene doped with boron difluoride β-ketoiminates have been synthesized. The luminescence properties of 12 dyes with various substituents have been studied. The effect of the boron difluoride β-ketoiminate concentration on the spectral properties of the samples has been studied. It has been found that the studied dyes exhibit monomer luminescence even with a tenfold increase in the luminophore concentration (from 0.05 to 0.5%). It has been revealed that composites containing boron difluoride 3-amino-1-phenyl-2-buten-1-onate (1a) and boron difluoride 3-methylamino-1-phenyl-2-buten-1-onate (2a) dyes in polystyrene exhibit exciplex luminescence.
doi_str_mv 10.1134/S0018143924700243
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subjects Boron
Chemistry
Chemistry and Materials Science
Difluorides
Dyes
Luminescence
Molecular Photonics
Optical properties
Physical Chemistry
Polymer matrix composites
Polymers
Polystyrene resins
title Spectral Properties of Polymer Composites Doped with Boron Difluoride β-Ketoiminates
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