Synthesis and Characterization of SiO2 Nanoparticles for Application as Nanoadsorbent to Clean Wastewater

• Published in: Coatings (Basel) 2024-07, Vol.14 (7), p.919
• Main Authors: Elizondo-Villarreal, Nora, Gandara-Martínez, Eleazar, García-Méndez, Manuel, Gracia-Pinilla, Miguel, Guzmán-Hernández, Ana María, Castaño, Víctor M., Gómez-Rodríguez, Cristian
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Aqueous solutions; Arsenic removal; Chemical synthesis; Colloiding; Controlled atmospheres; Copper; Crystal structure; Disinfection & disinfectants; Dyes; Efficiency; Energy consumption; Environmental risk; Liquid phases; Metal oxides; Metals; Methylene blue; Nanomaterials; Nanoparticles; Nanotechnology; Organic chemicals; Pesticides; Pollutants; Production costs; Silicon; Silicon dioxide; Sodium silicates; Sol-gel processes; Tetraethyl orthosilicate; Water treatment; Zinc oxides
• ISSN: 2079-6412; 2079-6412
• DOI: 10.3390/coatings14070919

By way of the sol–gel chemical synthesis method, it is possible to synthesize SiO2 nanoparticles with a defined specific particle size, a surface area, and a defined crystal structure that can be effectively used as a nanoadsorbent to remove various organic dyes. SiO2 nanoparticles were synthesized by the sol–gel method using sodium silicate (Na2SiO3) by a green method without using a tetraethyl orthosilicate (TEOS) precursor, which is very expensive and highly toxic. This sol–gel process involves the formation of a colloidal suspension (sol) and solid gelation to form a network in a continuous liquid phase (gel). In addition, it requires controlled atmospheres. XRD indicates the presence of an amorphous phase with a diffraction angle of 2θ = 23°, associated with SiO2. UV-Vis spectroscopy reveals an absorbance value in the region of 200 nm to 300 nm, associated with SiO2 nanoparticles. The application as a nanoadsorbent to remove dyes was measured, and it was found that the nanoparticles with the best performance were those that were synthesized with pH 7, showing a 97% removal with 20 mg of SiO2 nanoparticles in 60 min. Therefore, SiO2 nanoparticles can be used as a nanoadsorbent, using a low-cost and scalable method for application to remove methylene blue in an aqueous medium.