Light-induced ligand-to-metal charge transfer of Fe()-OR species in organic synthesis

Light-induced ligand-to-metal charge transfer (LMCT) has been utilized as a powerful strategy in various organic reactions. First-row transition metals, especially iron complexes, show good applications in this process. Fe( iii )-Cl and Fe( iii )-OR species are two key intermediates involved in the...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2024-07, Vol.22 (3), p.634-644
Main Authors: Qin, Jie, Lei, Hong, Gao, Chuanhua, Zheng, Yuewen, Zhao, Yating, Xia, Wujiong
Format: Article
Language:English
Subjects:
Charge transfer
Chemical reactions
Heavy metals
Intermediates
Iron
Ligands
Substrates
Transition metals
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Summary:Light-induced ligand-to-metal charge transfer (LMCT) has been utilized as a powerful strategy in various organic reactions. First-row transition metals, especially iron complexes, show good applications in this process. Fe( iii )-Cl and Fe( iii )-OR species are two key intermediates involved in the LMCT of iron complexes. This review highlights studies on LMCT of Fe( iii )-OR species, including carboxylate-iron and alkoxy-iron species, in organic transformations. Reaction conditions, substrate scope and related mechanisms are discussed. This review highlights studies on ligand-to-metal charge transfer of Fe( iii )-OR species in organic transformations.
ISSN:1477-0520
1477-0539
1477-0539
DOI:10.1039/d4ob00876f