Investigation of mechanical properties and self‐healing efficiency of carbon fibers composites infused with unsaturated polyester vitrimer

• Published in: Polymer composites 2024-08, Vol.45 (11), p.10404-10417
• Main Authors: Rizzo, Giuliana, Prasad, Vishnu, Yasar, Miray, Cicala, Gianluca, Ivankovic, Alojz, Murphy, Neal, Latteri, Alberta
• Format: Article
• Language: English
• Subjects: Carbon fiber reinforced plastics; CF's composites; Fiber composites; Healing; Interfacial shear strength; Laminates; Manufacturing; Mechanical properties; Polyester resins; Polyesters; Reprocessing; Resins; self‐healing; Shear strength; Thermodynamic properties; Transesterification; unsaturated polyester resins; Vitrimers; Wind damage
• ISSN: 0272-8397; 1548-0569
• DOI: 10.1002/pc.28483

Unsaturated polyester resins (UPR) are widely in composite manufacturing, particularly in the energy, wind, and construction sectors. When these composites sustain damage, defects or cracks, several methodologies are employed to heal and repair them to extend their lifespan while reducing environmental impacts. In this work, the use of vitrimeric UPR (UPRv) as a matrix for carbon fiber composite, was investigated in terms of healing efficiency by mechanical and thermal properties. Flexural and interlaminar shear strength tests revealed healing efficiencies exceeding 40% and 90%, respectively. These results were attributed to the transesterification exchange occurring within the crosslinked networks of UPRv. As described in our previous work, the incorporation of “Covalent Adaptable Networks (CANs)” enables the conversion of commercial thermoset (UPR) into vitrimeric resins, thereby providing reprocessing and healing capabilities. Furthermore, a comparison between pristine and healed composites with Mode I DCB and Mode II ENF tests, confirm how the introduction of vitrimer in composite facilitates the manufacturing of a self‐healing product, with a significant recovery of the original properties. Highlights Application of a previous synthetized vitrimeric unsaturated polyester resin (UPRv)—fabrication of CF's composites reinforced with UPRv—investigation of the self‐healing property of the developed laminates—potential application as green and sustainable composites. Self‐healing treatment carried out on damaged composite infused with polyester vitrimer.