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Effect of Hold Time on Electrical Properties of Lithium Zinc Borate Glass Ceramics for Energy Storage Applications
Conductivity spectra of heat-treated 50B 2 O 3 ·30Li 2 O·20ZnO glass samples for different hold times, 2 h, 4 h, 6 h, and 8 h, were investigated across a wide temperature range (413–573 K) and frequency range (0.1–10 6 Hz). Parameters like crossover frequency ( ω H ), frequency exponent (s), and di...
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| Published in: | Journal of electronic materials 2024-09, Vol.53 (9), p.5682-5695 |
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| container_title | Journal of electronic materials |
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| creator | Pawaria, Suman Ahlawat, Jyoti Sharma, Preeti Ohlan, Anil Dahiya, Sajjan Punia, Rajesh Maan, Anup Singh |
| description | Conductivity spectra of heat-treated 50B
2
O
3
·30Li
2
O·20ZnO glass samples for different hold times, 2 h, 4 h, 6 h, and 8 h, were investigated across a wide temperature range (413–573 K) and frequency range (0.1–10
6
Hz). Parameters like crossover frequency (
ω
H
), frequency exponent (s), and direct current conductivity (
σ
dc
) have been retrieved from the Almond West model fit of the experimental data of ac conductivity. The applicability of overlapping large polaron tunneling has been observed in the examined glass ceramics system. The activation energy determined from the conductivity, electric modulus, and impedance analysis shows a consistent trend. The glass composition 50B
2
O
3
·30Li
2
O·20ZnO exhibits the highest value of conductivity ~ 8.3 × 10
−6
Scm
−1
when crystallized for 4 h at 573 K, making it an ideal choice for electrode material in energy storage devices. An enhancement in electrical conductivity was observed by converting the 50B
2
O
3
·30Li
2
O·20ZnO glass samples into glass ceramics. Formation of the layered structure was observed from SEM micrographs, which indicates that the studied glass ceramics are appropriate for electric double-layer capacitance fabrication (EDLC). |
| doi_str_mv | 10.1007/s11664-024-11265-9 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3087046960</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3087046960</sourcerecordid><originalsourceid>FETCH-LOGICAL-c200t-74ad1a5598f6814d35247439b82620b6f288f0cf5f539aeed3585190da42a54f3</originalsourceid><addsrcrecordid>eNp9kE1LAzEURYMoWKt_wFXAdTTfk1lqqa1QULCCuAnpTFJTZiZjMl3035s6gjtXDy7n3gcHgGuCbwnGxV0iREqOMOWIECoFKk_AhAjOEFHy_RRMMJMECcrEObhIaYcxEUSRCYhz52w1wODgMjQ1XPvWwtDBeZPT6CvTwJcYehsHb9ORWvnh0-9b-OG7Cj6EaAYLF41JCc5sNK2vEnQhwnln4_YAX4dMbC287_smjw0-dOkSnDnTJHv1e6fg7XG-ni3R6nnxNLtfoYpiPKCCm5oYIUrlpCK8ZoLygrNyo6ikeCMdVcrhygknWGmszYASpMS14dQI7tgU3Iy7fQxfe5sGvQv72OWXmmFVYC5LiTNFR6qKIaVone6jb008aIL10a0e3ersVv-41WUusbGUMtxtbfyb_qf1DQYSe-c</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3087046960</pqid></control><display><type>article</type><title>Effect of Hold Time on Electrical Properties of Lithium Zinc Borate Glass Ceramics for Energy Storage Applications</title><source>Springer Link</source><creator>Pawaria, Suman ; Ahlawat, Jyoti ; Sharma, Preeti ; Ohlan, Anil ; Dahiya, Sajjan ; Punia, Rajesh ; Maan, Anup Singh</creator><creatorcontrib>Pawaria, Suman ; Ahlawat, Jyoti ; Sharma, Preeti ; Ohlan, Anil ; Dahiya, Sajjan ; Punia, Rajesh ; Maan, Anup Singh</creatorcontrib><description>Conductivity spectra of heat-treated 50B
2
O
3
·30Li
2
O·20ZnO glass samples for different hold times, 2 h, 4 h, 6 h, and 8 h, were investigated across a wide temperature range (413–573 K) and frequency range (0.1–10
6
Hz). Parameters like crossover frequency (
ω
H
), frequency exponent (s), and direct current conductivity (
σ
dc
) have been retrieved from the Almond West model fit of the experimental data of ac conductivity. The applicability of overlapping large polaron tunneling has been observed in the examined glass ceramics system. The activation energy determined from the conductivity, electric modulus, and impedance analysis shows a consistent trend. The glass composition 50B
2
O
3
·30Li
2
O·20ZnO exhibits the highest value of conductivity ~ 8.3 × 10
−6
Scm
−1
when crystallized for 4 h at 573 K, making it an ideal choice for electrode material in energy storage devices. An enhancement in electrical conductivity was observed by converting the 50B
2
O
3
·30Li
2
O·20ZnO glass samples into glass ceramics. Formation of the layered structure was observed from SEM micrographs, which indicates that the studied glass ceramics are appropriate for electric double-layer capacitance fabrication (EDLC).</description><identifier>ISSN: 0361-5235</identifier><identifier>EISSN: 1543-186X</identifier><identifier>DOI: 10.1007/s11664-024-11265-9</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Crystallization ; Direct current ; Electrical properties ; Electrical resistivity ; Electrode materials ; Electronics and Microelectronics ; Energy storage ; Frequency ranges ; Glass ceramics ; Heat treatment ; Instrumentation ; Lithium ; Materials Science ; Optical and Electronic Materials ; Original Research Article ; Photomicrographs ; Solid State Physics ; Zinc borate</subject><ispartof>Journal of electronic materials, 2024-09, Vol.53 (9), p.5682-5695</ispartof><rights>The Minerals, Metals & Materials Society 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-74ad1a5598f6814d35247439b82620b6f288f0cf5f539aeed3585190da42a54f3</cites><orcidid>0000-0002-5071-3696</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Pawaria, Suman</creatorcontrib><creatorcontrib>Ahlawat, Jyoti</creatorcontrib><creatorcontrib>Sharma, Preeti</creatorcontrib><creatorcontrib>Ohlan, Anil</creatorcontrib><creatorcontrib>Dahiya, Sajjan</creatorcontrib><creatorcontrib>Punia, Rajesh</creatorcontrib><creatorcontrib>Maan, Anup Singh</creatorcontrib><title>Effect of Hold Time on Electrical Properties of Lithium Zinc Borate Glass Ceramics for Energy Storage Applications</title><title>Journal of electronic materials</title><addtitle>J. Electron. Mater</addtitle><description>Conductivity spectra of heat-treated 50B
2
O
3
·30Li
2
O·20ZnO glass samples for different hold times, 2 h, 4 h, 6 h, and 8 h, were investigated across a wide temperature range (413–573 K) and frequency range (0.1–10
6
Hz). Parameters like crossover frequency (
ω
H
), frequency exponent (s), and direct current conductivity (
σ
dc
) have been retrieved from the Almond West model fit of the experimental data of ac conductivity. The applicability of overlapping large polaron tunneling has been observed in the examined glass ceramics system. The activation energy determined from the conductivity, electric modulus, and impedance analysis shows a consistent trend. The glass composition 50B
2
O
3
·30Li
2
O·20ZnO exhibits the highest value of conductivity ~ 8.3 × 10
−6
Scm
−1
when crystallized for 4 h at 573 K, making it an ideal choice for electrode material in energy storage devices. An enhancement in electrical conductivity was observed by converting the 50B
2
O
3
·30Li
2
O·20ZnO glass samples into glass ceramics. Formation of the layered structure was observed from SEM micrographs, which indicates that the studied glass ceramics are appropriate for electric double-layer capacitance fabrication (EDLC).</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Crystallization</subject><subject>Direct current</subject><subject>Electrical properties</subject><subject>Electrical resistivity</subject><subject>Electrode materials</subject><subject>Electronics and Microelectronics</subject><subject>Energy storage</subject><subject>Frequency ranges</subject><subject>Glass ceramics</subject><subject>Heat treatment</subject><subject>Instrumentation</subject><subject>Lithium</subject><subject>Materials Science</subject><subject>Optical and Electronic Materials</subject><subject>Original Research Article</subject><subject>Photomicrographs</subject><subject>Solid State Physics</subject><subject>Zinc borate</subject><issn>0361-5235</issn><issn>1543-186X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEURYMoWKt_wFXAdTTfk1lqqa1QULCCuAnpTFJTZiZjMl3035s6gjtXDy7n3gcHgGuCbwnGxV0iREqOMOWIECoFKk_AhAjOEFHy_RRMMJMECcrEObhIaYcxEUSRCYhz52w1wODgMjQ1XPvWwtDBeZPT6CvTwJcYehsHb9ORWvnh0-9b-OG7Cj6EaAYLF41JCc5sNK2vEnQhwnln4_YAX4dMbC287_smjw0-dOkSnDnTJHv1e6fg7XG-ni3R6nnxNLtfoYpiPKCCm5oYIUrlpCK8ZoLygrNyo6ikeCMdVcrhygknWGmszYASpMS14dQI7tgU3Iy7fQxfe5sGvQv72OWXmmFVYC5LiTNFR6qKIaVone6jb008aIL10a0e3ersVv-41WUusbGUMtxtbfyb_qf1DQYSe-c</recordid><startdate>20240901</startdate><enddate>20240901</enddate><creator>Pawaria, Suman</creator><creator>Ahlawat, Jyoti</creator><creator>Sharma, Preeti</creator><creator>Ohlan, Anil</creator><creator>Dahiya, Sajjan</creator><creator>Punia, Rajesh</creator><creator>Maan, Anup Singh</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-5071-3696</orcidid></search><sort><creationdate>20240901</creationdate><title>Effect of Hold Time on Electrical Properties of Lithium Zinc Borate Glass Ceramics for Energy Storage Applications</title><author>Pawaria, Suman ; Ahlawat, Jyoti ; Sharma, Preeti ; Ohlan, Anil ; Dahiya, Sajjan ; Punia, Rajesh ; Maan, Anup Singh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-74ad1a5598f6814d35247439b82620b6f288f0cf5f539aeed3585190da42a54f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Crystallization</topic><topic>Direct current</topic><topic>Electrical properties</topic><topic>Electrical resistivity</topic><topic>Electrode materials</topic><topic>Electronics and Microelectronics</topic><topic>Energy storage</topic><topic>Frequency ranges</topic><topic>Glass ceramics</topic><topic>Heat treatment</topic><topic>Instrumentation</topic><topic>Lithium</topic><topic>Materials Science</topic><topic>Optical and Electronic Materials</topic><topic>Original Research Article</topic><topic>Photomicrographs</topic><topic>Solid State Physics</topic><topic>Zinc borate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pawaria, Suman</creatorcontrib><creatorcontrib>Ahlawat, Jyoti</creatorcontrib><creatorcontrib>Sharma, Preeti</creatorcontrib><creatorcontrib>Ohlan, Anil</creatorcontrib><creatorcontrib>Dahiya, Sajjan</creatorcontrib><creatorcontrib>Punia, Rajesh</creatorcontrib><creatorcontrib>Maan, Anup Singh</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of electronic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pawaria, Suman</au><au>Ahlawat, Jyoti</au><au>Sharma, Preeti</au><au>Ohlan, Anil</au><au>Dahiya, Sajjan</au><au>Punia, Rajesh</au><au>Maan, Anup Singh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Hold Time on Electrical Properties of Lithium Zinc Borate Glass Ceramics for Energy Storage Applications</atitle><jtitle>Journal of electronic materials</jtitle><stitle>J. Electron. Mater</stitle><date>2024-09-01</date><risdate>2024</risdate><volume>53</volume><issue>9</issue><spage>5682</spage><epage>5695</epage><pages>5682-5695</pages><issn>0361-5235</issn><eissn>1543-186X</eissn><abstract>Conductivity spectra of heat-treated 50B
2
O
3
·30Li
2
O·20ZnO glass samples for different hold times, 2 h, 4 h, 6 h, and 8 h, were investigated across a wide temperature range (413–573 K) and frequency range (0.1–10
6
Hz). Parameters like crossover frequency (
ω
H
), frequency exponent (s), and direct current conductivity (
σ
dc
) have been retrieved from the Almond West model fit of the experimental data of ac conductivity. The applicability of overlapping large polaron tunneling has been observed in the examined glass ceramics system. The activation energy determined from the conductivity, electric modulus, and impedance analysis shows a consistent trend. The glass composition 50B
2
O
3
·30Li
2
O·20ZnO exhibits the highest value of conductivity ~ 8.3 × 10
−6
Scm
−1
when crystallized for 4 h at 573 K, making it an ideal choice for electrode material in energy storage devices. An enhancement in electrical conductivity was observed by converting the 50B
2
O
3
·30Li
2
O·20ZnO glass samples into glass ceramics. Formation of the layered structure was observed from SEM micrographs, which indicates that the studied glass ceramics are appropriate for electric double-layer capacitance fabrication (EDLC).</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11664-024-11265-9</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-5071-3696</orcidid></addata></record> |
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| ispartof | Journal of electronic materials, 2024-09, Vol.53 (9), p.5682-5695 |
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| language | eng |
| recordid | cdi_proquest_journals_3087046960 |
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| subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Crystallization Direct current Electrical properties Electrical resistivity Electrode materials Electronics and Microelectronics Energy storage Frequency ranges Glass ceramics Heat treatment Instrumentation Lithium Materials Science Optical and Electronic Materials Original Research Article Photomicrographs Solid State Physics Zinc borate |
| title | Effect of Hold Time on Electrical Properties of Lithium Zinc Borate Glass Ceramics for Energy Storage Applications |
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