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Thermodynamic Study of Tellurium Polybromide Complexes
The pressure of saturated and unsaturated Br 2 vapors over (cation) 2 {[TeBr 6 ](Br 2 )} (cation = Me 4 N + , Et 4 N + ) solid polybromotellurates is measured via static tensimetry using membrane zero manometers in a wide range of temperatures. Experimental data are used to determine the thermal sta...
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| Published in: | Russian Journal of Physical Chemistry A 2024, Vol.98 (1), p.50-56 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| container_end_page | 56 |
| container_issue | 1 |
| container_start_page | 50 |
| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 98 |
| creator | Zelenina, L. N. Chusova, T. P. Korobeinikov, N. A. Usol’tsev, A. N. |
| description | The pressure of saturated and unsaturated Br
2
vapors over (cation)
2
{[TeBr
6
](Br
2
)} (cation = Me
4
N
+
, Et
4
N
+
) solid polybromotellurates is measured via static tensimetry using membrane zero manometers in a wide range of temperatures. Experimental data are used to determine the thermal stability of these compounds (
T
dec
). A physicochemical model of vaporization is proven, thermodynamic characteristics of the evaporation of bromine that bonds the moieties of polybromotellurate anions (
,
,
=
f
(
T
)) are calculated, and the energies of bonding between [TeBr
6
] octahedra and Br
2
(
) are determined. Results are compared to others for bismuth polybromide complexes studied earlier. |
| doi_str_mv | 10.1134/S003602442401031X |
| format | article |
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2
vapors over (cation)
2
{[TeBr
6
](Br
2
)} (cation = Me
4
N
+
, Et
4
N
+
) solid polybromotellurates is measured via static tensimetry using membrane zero manometers in a wide range of temperatures. Experimental data are used to determine the thermal stability of these compounds (
T
dec
). A physicochemical model of vaporization is proven, thermodynamic characteristics of the evaporation of bromine that bonds the moieties of polybromotellurate anions (
,
,
=
f
(
T
)) are calculated, and the energies of bonding between [TeBr
6
] octahedra and Br
2
(
) are determined. Results are compared to others for bismuth polybromide complexes studied earlier.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S003602442401031X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Bismuth ; Bromine compounds ; Cations ; Chemical bonds ; Chemistry ; Chemistry and Materials Science ; Physical Chemistry ; Tellurium ; Thermal stability ; Thermodynamics ; Thermodynamics and Materials Science ; Vaporization</subject><ispartof>Russian Journal of Physical Chemistry A, 2024, Vol.98 (1), p.50-56</ispartof><rights>Pleiades Publishing, Ltd. 2024. ISSN 0036-0244, Russian Journal of Physical Chemistry A, 2024, Vol. 98, No. 1, pp. 50–56. © Pleiades Publishing, Ltd., 2024. ISSN 0036-0244, Russian Journal of Physical Chemistry A, 2024. © Pleiades Publishing, Ltd., 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-2d9af5ab40d4cdc8520fc20d013bd5c595eab976c41b8fe0571e6e6962e1b9193</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Zelenina, L. N.</creatorcontrib><creatorcontrib>Chusova, T. P.</creatorcontrib><creatorcontrib>Korobeinikov, N. A.</creatorcontrib><creatorcontrib>Usol’tsev, A. N.</creatorcontrib><title>Thermodynamic Study of Tellurium Polybromide Complexes</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>The pressure of saturated and unsaturated Br
2
vapors over (cation)
2
{[TeBr
6
](Br
2
)} (cation = Me
4
N
+
, Et
4
N
+
) solid polybromotellurates is measured via static tensimetry using membrane zero manometers in a wide range of temperatures. Experimental data are used to determine the thermal stability of these compounds (
T
dec
). A physicochemical model of vaporization is proven, thermodynamic characteristics of the evaporation of bromine that bonds the moieties of polybromotellurate anions (
,
,
=
f
(
T
)) are calculated, and the energies of bonding between [TeBr
6
] octahedra and Br
2
(
) are determined. Results are compared to others for bismuth polybromide complexes studied earlier.</description><subject>Bismuth</subject><subject>Bromine compounds</subject><subject>Cations</subject><subject>Chemical bonds</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Physical Chemistry</subject><subject>Tellurium</subject><subject>Thermal stability</subject><subject>Thermodynamics</subject><subject>Thermodynamics and Materials Science</subject><subject>Vaporization</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kE1Lw0AURQdRsFZ_gLuA6-h789XMUopaoaDQCt2FZOZFU5JOnUnA_HtTKrgQV29xz7kPLmPXCLeIQt6tAIQGLiWXgCBwc8ImqASmmRabUzY5xOkhP2cXMW4BpJQoJ0yvPyi03g27oq1tsup6NyS-StbUNH2o-zZ59c1QBt_WjpK5b_cNfVG8ZGdV0US6-rlT9vb4sJ4v0uXL0_P8fplarrMu5c4UlSpKCU5aZzPFobIcHKAonbLKKCpKM9NWYplVBGqGpEkbzQlLg0ZM2c2xdx_8Z0-xy7e-D7vxZS7AgOFazcRI4ZGywccYqMr3oW6LMOQI-WGe_M88o8OPThzZ3TuF3-b_pW-EjGZw</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Zelenina, L. N.</creator><creator>Chusova, T. P.</creator><creator>Korobeinikov, N. A.</creator><creator>Usol’tsev, A. N.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2024</creationdate><title>Thermodynamic Study of Tellurium Polybromide Complexes</title><author>Zelenina, L. N. ; Chusova, T. P. ; Korobeinikov, N. A. ; Usol’tsev, A. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-2d9af5ab40d4cdc8520fc20d013bd5c595eab976c41b8fe0571e6e6962e1b9193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Bismuth</topic><topic>Bromine compounds</topic><topic>Cations</topic><topic>Chemical bonds</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Physical Chemistry</topic><topic>Tellurium</topic><topic>Thermal stability</topic><topic>Thermodynamics</topic><topic>Thermodynamics and Materials Science</topic><topic>Vaporization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zelenina, L. N.</creatorcontrib><creatorcontrib>Chusova, T. P.</creatorcontrib><creatorcontrib>Korobeinikov, N. A.</creatorcontrib><creatorcontrib>Usol’tsev, A. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zelenina, L. N.</au><au>Chusova, T. P.</au><au>Korobeinikov, N. A.</au><au>Usol’tsev, A. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermodynamic Study of Tellurium Polybromide Complexes</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2024</date><risdate>2024</risdate><volume>98</volume><issue>1</issue><spage>50</spage><epage>56</epage><pages>50-56</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>The pressure of saturated and unsaturated Br
2
vapors over (cation)
2
{[TeBr
6
](Br
2
)} (cation = Me
4
N
+
, Et
4
N
+
) solid polybromotellurates is measured via static tensimetry using membrane zero manometers in a wide range of temperatures. Experimental data are used to determine the thermal stability of these compounds (
T
dec
). A physicochemical model of vaporization is proven, thermodynamic characteristics of the evaporation of bromine that bonds the moieties of polybromotellurate anions (
,
,
=
f
(
T
)) are calculated, and the energies of bonding between [TeBr
6
] octahedra and Br
2
(
) are determined. Results are compared to others for bismuth polybromide complexes studied earlier.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S003602442401031X</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-0244 |
| ispartof | Russian Journal of Physical Chemistry A, 2024, Vol.98 (1), p.50-56 |
| issn | 0036-0244 1531-863X |
| language | eng |
| recordid | cdi_proquest_journals_3090926573 |
| source | Springer Nature |
| subjects | Bismuth Bromine compounds Cations Chemical bonds Chemistry Chemistry and Materials Science Physical Chemistry Tellurium Thermal stability Thermodynamics Thermodynamics and Materials Science Vaporization |
| title | Thermodynamic Study of Tellurium Polybromide Complexes |
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