Synthesis and crystal structure of a new 1D metal–organic coordination polymer with Cu2+ ions based on a chiral terephthalic acid derivative synthesized for the first time

The new homochiral 1D metal–organic coordination polymer {Cu[bdc-(N-MePro)H2O]·0.25H2O}n was synthesized using 2-[(1-methyl-l-prolyl)amino]terephthalic acid, which was obtained for the first time. The unique crystal structure of the new compound was determined using powder X-ray diffraction. The cat...

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Bibliographic Details
Published in:CrystEngComm 2024-08, Vol.26 (32), p.4305-4312
Main Authors: Veselovsky, Vladimir V, Isaeva, Vera I, Nissenbaum, Vera D, Chernyshev, Vladimir V
Format: Article
Language:English
Subjects:
Aniline
Chemical synthesis
Coordination polymers
Copper
Crystal structure
Ring opening
Terephthalic acid
X ray powder diffraction
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Summary:The new homochiral 1D metal–organic coordination polymer {Cu[bdc-(N-MePro)H2O]·0.25H2O}n was synthesized using 2-[(1-methyl-l-prolyl)amino]terephthalic acid, which was obtained for the first time. The unique crystal structure of the new compound was determined using powder X-ray diffraction. The catalytic performance of {Cu[bdc-(N-MePro)H2O]·0.25H2O}n in the asymmetric ring opening reactions of styrene oxide and cyclohexene oxide with aniline was evaluated.
ISSN:1466-8033
DOI:10.1039/d4ce00408f