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Crystal Structure of Lanthanide Salts with 2,4-Dichlorophenoxyacetic Acid
Compounds of three types, [LnL 3 (C 2 H 5 OH)] (Ln = Nd ( I ), Sm ( II ), Eu ( III )), [LnL 3 (H 2 O)] (Ln = Gd ( IV ), Tb ( V )), and [DyL 2 (NO 3 )(C 2 H 5 OH) 2 ] ( VI ), were obtained by reactions of lanthanide nitrate with NaL (L – = 2,4-dichlorophenoxyacetate anion) in ethanol. The composition...
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| Published in: | Russian journal of coordination chemistry 2024-07, Vol.50 (7), p.476-484 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| container_end_page | 484 |
| container_issue | 7 |
| container_start_page | 476 |
| container_title | Russian journal of coordination chemistry |
| container_volume | 50 |
| creator | Kiskin, M. A. Konnik, O. V. Shul’gin, V. F. Gusev, A. N. |
| description | Compounds of three types, [LnL
3
(C
2
H
5
OH)] (Ln = Nd (
I
), Sm (
II
), Eu (
III
)), [LnL
3
(H
2
O)] (Ln = Gd (
IV
), Tb (
V
)), and [DyL
2
(NO
3
)(C
2
H
5
OH)
2
] (
VI
), were obtained by reactions of lanthanide nitrate with NaL (L
–
= 2,4-dichlorophenoxyacetate anion) in ethanol. The composition and structure of complexes
I
–
VI
were investigated by elemental and thermogravimetric analysis, IR spectroscopy, and X-ray diffraction (nos. 2311578 (
I
), 2311579 (
II
), 2311580 (
III
), 2311581 (
IV
), 2311582 (
VI
)). All compounds have a one-dimensional polymer structure in which metal atoms are connected by bridging carboxylate groups. The π–π interactions and intermolecular contacts between the chains give rise to a three-dimensional supramolecular structure. |
| doi_str_mv | 10.1134/S107032842460030X |
| format | article |
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3
(C
2
H
5
OH)] (Ln = Nd (
I
), Sm (
II
), Eu (
III
)), [LnL
3
(H
2
O)] (Ln = Gd (
IV
), Tb (
V
)), and [DyL
2
(NO
3
)(C
2
H
5
OH)
2
] (
VI
), were obtained by reactions of lanthanide nitrate with NaL (L
–
= 2,4-dichlorophenoxyacetate anion) in ethanol. The composition and structure of complexes
I
–
VI
were investigated by elemental and thermogravimetric analysis, IR spectroscopy, and X-ray diffraction (nos. 2311578 (
I
), 2311579 (
II
), 2311580 (
III
), 2311581 (
IV
), 2311582 (
VI
)). All compounds have a one-dimensional polymer structure in which metal atoms are connected by bridging carboxylate groups. The π–π interactions and intermolecular contacts between the chains give rise to a three-dimensional supramolecular structure.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S107032842460030X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic structure ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Dichlorophenoxyacetic acid ; Ethanol ; Gadolinium ; Infrared spectroscopy ; Inorganic Chemistry ; Molecular chains ; Physical Chemistry ; Samarium ; Samarium compounds ; Thermogravimetric analysis</subject><ispartof>Russian journal of coordination chemistry, 2024-07, Vol.50 (7), p.476-484</ispartof><rights>Pleiades Publishing, Ltd. 2024. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2024, Vol. 50, No. 7, pp. 476–484. © Pleiades Publishing, Ltd., 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c198t-69c16e97154eff05592bd9e9b0832e10eed4b9c210c80b7b58f83c5609a3acfe3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Kiskin, M. A.</creatorcontrib><creatorcontrib>Konnik, O. V.</creatorcontrib><creatorcontrib>Shul’gin, V. F.</creatorcontrib><creatorcontrib>Gusev, A. N.</creatorcontrib><title>Crystal Structure of Lanthanide Salts with 2,4-Dichlorophenoxyacetic Acid</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>Compounds of three types, [LnL
3
(C
2
H
5
OH)] (Ln = Nd (
I
), Sm (
II
), Eu (
III
)), [LnL
3
(H
2
O)] (Ln = Gd (
IV
), Tb (
V
)), and [DyL
2
(NO
3
)(C
2
H
5
OH)
2
] (
VI
), were obtained by reactions of lanthanide nitrate with NaL (L
–
= 2,4-dichlorophenoxyacetate anion) in ethanol. The composition and structure of complexes
I
–
VI
were investigated by elemental and thermogravimetric analysis, IR spectroscopy, and X-ray diffraction (nos. 2311578 (
I
), 2311579 (
II
), 2311580 (
III
), 2311581 (
IV
), 2311582 (
VI
)). All compounds have a one-dimensional polymer structure in which metal atoms are connected by bridging carboxylate groups. The π–π interactions and intermolecular contacts between the chains give rise to a three-dimensional supramolecular structure.</description><subject>Atomic structure</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Dichlorophenoxyacetic acid</subject><subject>Ethanol</subject><subject>Gadolinium</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Molecular chains</subject><subject>Physical Chemistry</subject><subject>Samarium</subject><subject>Samarium compounds</subject><subject>Thermogravimetric analysis</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kE9Lw0AQxRdRsFY_gLcFr0ZnsvmzeyzVaqHgoQrewmYza1JiUnc3aL-9KRU8iKd58N77DTzGLhFuEEVyu0bIQcQyiZMMQMDrEZtgBjISAuXxqEc72vun7Mz7DQACpGrClnO380G3fB3cYMLgiPeWr3QXat01FfG1boPnn02oeXydRHeNqdve9duauv5rpw2FxvCZaapzdmJ16-ni507Zy-L-ef4YrZ4elvPZKjKoZIgyZTAjlWOakLWQpiouK0WqBCliQiCqklKZGMFIKPMylVYKk2agtNDGkpiyqwN36_qPgXwoNv3guvFlIUCNvDyBfEzhIWVc770jW2xd867drkAo9osVfxYbO_Gh48ds90bul_x_6RvM0myH</recordid><startdate>20240701</startdate><enddate>20240701</enddate><creator>Kiskin, M. A.</creator><creator>Konnik, O. V.</creator><creator>Shul’gin, V. F.</creator><creator>Gusev, A. N.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240701</creationdate><title>Crystal Structure of Lanthanide Salts with 2,4-Dichlorophenoxyacetic Acid</title><author>Kiskin, M. A. ; Konnik, O. V. ; Shul’gin, V. F. ; Gusev, A. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c198t-69c16e97154eff05592bd9e9b0832e10eed4b9c210c80b7b58f83c5609a3acfe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Atomic structure</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Dichlorophenoxyacetic acid</topic><topic>Ethanol</topic><topic>Gadolinium</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Molecular chains</topic><topic>Physical Chemistry</topic><topic>Samarium</topic><topic>Samarium compounds</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kiskin, M. A.</creatorcontrib><creatorcontrib>Konnik, O. V.</creatorcontrib><creatorcontrib>Shul’gin, V. F.</creatorcontrib><creatorcontrib>Gusev, A. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kiskin, M. A.</au><au>Konnik, O. V.</au><au>Shul’gin, V. F.</au><au>Gusev, A. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal Structure of Lanthanide Salts with 2,4-Dichlorophenoxyacetic Acid</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2024-07-01</date><risdate>2024</risdate><volume>50</volume><issue>7</issue><spage>476</spage><epage>484</epage><pages>476-484</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>Compounds of three types, [LnL
3
(C
2
H
5
OH)] (Ln = Nd (
I
), Sm (
II
), Eu (
III
)), [LnL
3
(H
2
O)] (Ln = Gd (
IV
), Tb (
V
)), and [DyL
2
(NO
3
)(C
2
H
5
OH)
2
] (
VI
), were obtained by reactions of lanthanide nitrate with NaL (L
–
= 2,4-dichlorophenoxyacetate anion) in ethanol. The composition and structure of complexes
I
–
VI
were investigated by elemental and thermogravimetric analysis, IR spectroscopy, and X-ray diffraction (nos. 2311578 (
I
), 2311579 (
II
), 2311580 (
III
), 2311581 (
IV
), 2311582 (
VI
)). All compounds have a one-dimensional polymer structure in which metal atoms are connected by bridging carboxylate groups. The π–π interactions and intermolecular contacts between the chains give rise to a three-dimensional supramolecular structure.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S107032842460030X</doi><tpages>9</tpages></addata></record> |
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| ispartof | Russian journal of coordination chemistry, 2024-07, Vol.50 (7), p.476-484 |
| issn | 1070-3284 1608-3318 |
| language | eng |
| recordid | cdi_proquest_journals_3095597407 |
| source | Springer Link |
| subjects | Atomic structure Chemistry Chemistry and Materials Science Crystal structure Dichlorophenoxyacetic acid Ethanol Gadolinium Infrared spectroscopy Inorganic Chemistry Molecular chains Physical Chemistry Samarium Samarium compounds Thermogravimetric analysis |
| title | Crystal Structure of Lanthanide Salts with 2,4-Dichlorophenoxyacetic Acid |
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